Catalytic total hydrodeoxygenation of biomass‐derived polyfunctionalized substrates to alkanes

Y Nakagawa, S Liu, M Tamura, K Tomishige - ChemSusChem, 2015 - Wiley Online Library
The total hydrodeoxygenation of carbohydrate‐derived molecules to alkanes, a key reaction
in the production of biofuel, was reviewed from the aspect of catalysis. Noble metals (or Ni) …

Catalytic selective ring opening of polyaromatics for cleaner transportation fuels

D Jampaiah, DY Murzin, AF Lee, D Schaller… - Energy & …, 2022 - pubs.rsc.org
The selective C–C bond cleavage of mono-and bicyclic naphthenic molecules via catalytic
ring opening plays a vital role in refining low-quality fossil oils and pyrolysis oils derived from …

Platinum and other transition metal nanoclusters (Pd, Rh) stabilized by PAMAM dendrimer as excellent heterogeneous catalysts: application to the …

C Deraedt, G Melaet, WT Ralston, R Ye… - Nano …, 2017 - ACS Publications
Pt, Rh, and Pd nanoclusters stabilized by PAMAM dendrimer are used for the first time in a
gas flow reactor at high temperature (150–250° C). Pt nanoclusters show a very high activity …

Theoretical and kinetic assessment of the mechanism of ethane hydrogenolysis on metal surfaces saturated with chemisorbed hydrogen

DW Flaherty, DD Hibbitts, EI Gürbüz, E Iglesia - Journal of catalysis, 2014 - Elsevier
Ethane hydrogenolysis involves C–C bond rupture in unsaturated species in quasi-
equilibrium with gaseous reactants and H 2 on metal clusters, because C–C bonds weaken …

Size and shape dependence on Pt nanoparticles for the methylcyclopentane/hydrogen ring opening/ring enlargement reaction

S Alayoglu, C Aliaga, C Sprung, GA Somorjai - Catalysis letters, 2011 - Springer
Abstract Monodisperse Pt nanoparticles (NPs) with well-controlled sizes in the range
between 1.5 and 10.8 nm, and shapes of octahedron, cube, truncated octahedron and …

Catalytic ring opening of cycloalkanes on Ir Clusters: alkyl substitution effects on the structure and stability of C–C bond cleavage transition states

DW Flaherty, A Uzun, E Iglesia - The Journal of Physical Chemistry …, 2015 - ACS Publications
Rates and locations of C–C cleavage during the hydrogenolysis of alkyl-cyclohexanes
determine the isomeric products of ring opening and the yield losses from dealkylation …

Ring opening of decalin and methylcyclohexane over alumina-based monofunctional WO3/Al2O3 and Ir/Al2O3 catalysts

R Moraes, K Thomas, S Thomas, S Van Donk… - Journal of …, 2012 - Elsevier
Ring-opening reactions of decalin and MCH were studied over monofunctional acid
(WO3/Al2O3) and metal (Ir/Al2O3) catalysts containing, respectively, up to 5.3 at. W/nm2 and …

Bimetallic Catalysts for Sustainable Chemistry: Surface Redox Reactions For Tuning The Catalytic Surface Composition

C Especel, G Lafaye, F Epron - ChemCatChem, 2023 - Wiley Online Library
The development of a bimetallic catalyst for a given reaction requires not only the selection
of the appropriate metals M1 and M2 but also the control as far as possible of the distribution …

[PDF][PDF] Catalytic hydrogenation of hydrocarbons for gasoline production

MD Garba, A Galadima - J. Phys. Sci, 2018 - academia.edu
The persistent growth in the global population has accounted for the continuous increase in
the use of gasoline-based automobile engines. Although the application of gasoline …

Influence of iridium content on the behavior of Pt-Ir/Al2O3 and Pt-Ir/TiO2 catalysts for selective ring opening of naphthenes

MA Vicerich, VM Benitez, C Especel, F Epron… - Applied Catalysis A …, 2013 - Elsevier
The influence of Ir content on the properties of Pt-Ir/Al2O3 and Pt-Ir/TiO2 catalysts for
selective ring opening of naphthenes was studied. It was found that these catalysts display a …