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Catalytic total hydrodeoxygenation of biomass‐derived polyfunctionalized substrates to alkanes
The total hydrodeoxygenation of carbohydrate‐derived molecules to alkanes, a key reaction
in the production of biofuel, was reviewed from the aspect of catalysis. Noble metals (or Ni) …
in the production of biofuel, was reviewed from the aspect of catalysis. Noble metals (or Ni) …
Catalytic selective ring opening of polyaromatics for cleaner transportation fuels
The selective C–C bond cleavage of mono-and bicyclic naphthenic molecules via catalytic
ring opening plays a vital role in refining low-quality fossil oils and pyrolysis oils derived from …
ring opening plays a vital role in refining low-quality fossil oils and pyrolysis oils derived from …
Platinum and other transition metal nanoclusters (Pd, Rh) stabilized by PAMAM dendrimer as excellent heterogeneous catalysts: application to the …
Pt, Rh, and Pd nanoclusters stabilized by PAMAM dendrimer are used for the first time in a
gas flow reactor at high temperature (150–250° C). Pt nanoclusters show a very high activity …
gas flow reactor at high temperature (150–250° C). Pt nanoclusters show a very high activity …
Theoretical and kinetic assessment of the mechanism of ethane hydrogenolysis on metal surfaces saturated with chemisorbed hydrogen
Ethane hydrogenolysis involves C–C bond rupture in unsaturated species in quasi-
equilibrium with gaseous reactants and H 2 on metal clusters, because C–C bonds weaken …
equilibrium with gaseous reactants and H 2 on metal clusters, because C–C bonds weaken …
Size and shape dependence on Pt nanoparticles for the methylcyclopentane/hydrogen ring opening/ring enlargement reaction
S Alayoglu, C Aliaga, C Sprung, GA Somorjai - Catalysis letters, 2011 - Springer
Abstract Monodisperse Pt nanoparticles (NPs) with well-controlled sizes in the range
between 1.5 and 10.8 nm, and shapes of octahedron, cube, truncated octahedron and …
between 1.5 and 10.8 nm, and shapes of octahedron, cube, truncated octahedron and …
Catalytic ring opening of cycloalkanes on Ir Clusters: alkyl substitution effects on the structure and stability of C–C bond cleavage transition states
Rates and locations of C–C cleavage during the hydrogenolysis of alkyl-cyclohexanes
determine the isomeric products of ring opening and the yield losses from dealkylation …
determine the isomeric products of ring opening and the yield losses from dealkylation …
Ring opening of decalin and methylcyclohexane over alumina-based monofunctional WO3/Al2O3 and Ir/Al2O3 catalysts
R Moraes, K Thomas, S Thomas, S Van Donk… - Journal of …, 2012 - Elsevier
Ring-opening reactions of decalin and MCH were studied over monofunctional acid
(WO3/Al2O3) and metal (Ir/Al2O3) catalysts containing, respectively, up to 5.3 at. W/nm2 and …
(WO3/Al2O3) and metal (Ir/Al2O3) catalysts containing, respectively, up to 5.3 at. W/nm2 and …
Bimetallic Catalysts for Sustainable Chemistry: Surface Redox Reactions For Tuning The Catalytic Surface Composition
C Especel, G Lafaye, F Epron - ChemCatChem, 2023 - Wiley Online Library
The development of a bimetallic catalyst for a given reaction requires not only the selection
of the appropriate metals M1 and M2 but also the control as far as possible of the distribution …
of the appropriate metals M1 and M2 but also the control as far as possible of the distribution …
[PDF][PDF] Catalytic hydrogenation of hydrocarbons for gasoline production
The persistent growth in the global population has accounted for the continuous increase in
the use of gasoline-based automobile engines. Although the application of gasoline …
the use of gasoline-based automobile engines. Although the application of gasoline …
Influence of iridium content on the behavior of Pt-Ir/Al2O3 and Pt-Ir/TiO2 catalysts for selective ring opening of naphthenes
The influence of Ir content on the properties of Pt-Ir/Al2O3 and Pt-Ir/TiO2 catalysts for
selective ring opening of naphthenes was studied. It was found that these catalysts display a …
selective ring opening of naphthenes was studied. It was found that these catalysts display a …