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Mechanochemical degradation and recycling of synthetic polymers
The accumulation of plastic waste, due to lack of recycling, has led to serious environmental
pollution. Although mechanical recycling can alleviate this issue, it inevitably reduces the …
pollution. Although mechanical recycling can alleviate this issue, it inevitably reduces the …
Mechanochemical tools for polymer materials
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …
failure and healing of polymer materials. The development of mechanophores–molecular …
Facile mechanochemical cycloreversion of polymer cross-linkers enhances tear resistance
The mechanical properties of covalent polymer networks often arise from the permanent end-
linking or cross-linking of polymer strands, and molecular linkers that break more easily …
linking or cross-linking of polymer strands, and molecular linkers that break more easily …
Covalent mechanochemistry and contemporary polymer network chemistry: A marriage in the making
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …
mechanophores that translate mechanical energy into a variety of functional responses …
Toughening hydrogels through force-triggered chemical reactions that lengthen polymer strands
The utility and lifetime of materials made from polymer networks, including hydrogels,
depend on their capacity to stretch and resist tearing. In gels and elastomers, those …
depend on their capacity to stretch and resist tearing. In gels and elastomers, those …
The many flavours of mechanochemistry and its plausible conceptual underpinnings
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …
chemical reactivity. The fuzziness of this definition means that it includes processes as …
The role of polymer mechanochemistry in responsive materials and additive manufacturing
The use of mechanical forces to chemically transform polymers dates back decades. In
recent years, the use of mechanochemistry to direct constructive transformations in polymers …
recent years, the use of mechanochemistry to direct constructive transformations in polymers …
Mechanical scission of a knotted polymer
Molecular knots and entanglements form randomly and spontaneously in both biological
and synthetic polymer chains. It is known that macroscopic materials, such as ropes, are …
and synthetic polymer chains. It is known that macroscopic materials, such as ropes, are …
Swelling-activated, soft mechanochemistry in polymer materials
Swelling in polymer materials is a ubiquitous phenomenon. At a molecular level, swelling is
dictated by solvent–polymer interactions, and has been thoroughly studied both theoretically …
dictated by solvent–polymer interactions, and has been thoroughly studied both theoretically …
Validation of the CoGEF method as a predictive tool for polymer mechanochemistry
The development of force-responsive molecules called mechanophores is a central
component of the field of polymer mechanochemistry. Mechanophores enable the design …
component of the field of polymer mechanochemistry. Mechanophores enable the design …