Azobenzene-containing bent-core liquid crystals: an overview

M Alaasar - Liquid Crystals, 2016 - Taylor & Francis
Azo-functionalised materials are of special interest due to their photochromic nature, ie
reversible trans–cis isomerisation upon photoirradiation. The combination of photosensitivity …

Molecular geometry, twist-bend nematic phase and unconventional elasticity: a generalised Maier–Saupe theory

C Greco, GR Luckhurst, A Ferrarini - Soft Matter, 2014 - pubs.rsc.org
It has been found that bent-shaped achiral molecules can form a liquid crystal phase, called
the Twist-Bend Nematic (NTB), which is locally polar and spontaneously twisted having a …

Local distortion energy and coarse-grained elasticity of the twist-bend nematic phase

C Meyer, I Dozov - Soft Matter, 2016 - pubs.rsc.org
The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, NTB,
has a doubly degenerate ground-state with a periodically modulated heliconical structure …

Fine-tuning the effect of π–π interactions on the stability of the N TB phase

A Knežević, M Sapunar, A Buljan, I Dokli, Z Hameršak… - Soft Matter, 2018 - pubs.rsc.org
The synthesis and liquid-crystalline properties are reported for novel bent-shaped dimers in
which a naphthyl group has been incorporated into the mesogenic cores. In addition to the …

Towards understanding the N TB phase: a combined experimental, computational and spectroscopic study

T Ivšić, M Vinković, U Baumeister, A Mikleušević… - RSC Advances, 2016 - pubs.rsc.org
Today liquid-crystalline materials are most widely exploited for flat-panel displays, and yet
their ability to self-organize into periodically ordered nanostructures gives rise to a broad …

[HTML][HTML] How do intermolecular interactions evolve at the nematic to twist–bent phase transition?

K Merkel, B Loska, Y Arakawa, GH Mehl… - International Journal of …, 2022 - mdpi.com
Polarized beam infrared (IR) spectroscopy provides valuable information on changes in the
orientation of samples in nematic phases, especially on the role of intermolecular …

Anomalously low twist and bend elastic constants in an oxadiazole-based bent-core nematic liquid crystal and its mixtures; contributions of spontaneous chirality and …

S Srigengan, M Nagaraj, A Ferrarini… - Journal of Materials …, 2018 - pubs.rsc.org
The splay, twist, and bend elastic constants of an oxadiazole based bent-core liquid crystal
have been measured as functions of temperature throughout the nematic phase. The splay …

Density functional theory of nematic elasticity: softening from the polar order

P De Gregorio, E Frezza, C Greco, A Ferrarini - Soft Matter, 2016 - pubs.rsc.org
Recent experiments have evidenced some unconventional features in the elasticity of
nematics, which cannot be explained by standard microscopic theories. Here, in the …

Microscopic modelling of nematic elastic constants beyond Straley theory

D Revignas, A Ferrarini - Soft Matter, 2022 - pubs.rsc.org
Recent findings on various classes of nematics, whose microscopic structure differs from the
prototypical rod-like shape, evidence unusual elastic properties, which challenge existing …

Recent NMR studies of thermotropic liquid crystals

RY Dong - Annual reports on NMR spectroscopy, 2016 - Elsevier
Solid state NMR pulse techniques have been found most useful to elucidate order and
dynamics of molecules of various shapes which can self-assemble into ordered fluids. This …