Covalent organic frameworks

KT Tan, S Ghosh, Z Wang, F Wen… - Nature Reviews …, 2023 - nature.com
The dream to prepare well-defined materials drives the methodological evolution for
molecular synthesis, structural control and materials manufacturing. Among various …

Recent advances in two-dimensional polymers: synthesis, assembly and energy-related applications

Y Ren, Y Xu - Chemical Society Reviews, 2024 - pubs.rsc.org
Two-dimensional polymers (2DPs) are a class of 2D crystalline polymer materials with
definite structures, which have outstanding physical–chemical and electronic properties …

Observing polymerization in 2D dynamic covalent polymers

G Zhan, ZF Cai, K Strutyński, L Yu, N Herrmann… - Nature, 2022 - nature.com
The quality of crystalline two-dimensional (2D) polymers,,,,–is intimately related to the
elusive polymerization and crystallization processes. Understanding the mechanism of such …

Fast water transport and molecular sieving through ultrathin ordered conjugated-polymer-framework membranes

J Shen, Y Cai, C Zhang, W Wei, C Chen, L Liu… - Nature Materials, 2022 - nature.com
The development of membranes that block solutes while allowing rapid water transport is of
great importance. The microstructure of the membrane needs to be rationally designed at …

Electronic and quantum properties of organic two-dimensional crystals

Z Wang, M Wang, T Heine, X Feng - Nature Reviews Materials, 2024 - nature.com
Organic two-dimensional crystals (O2DCs) are a class of synthetic layered materials,
typically constructed from π-conjugated building blocks, that show extended in-plane π …

Two-Dimensional Organic–Inorganic van der Waals Hybrids

F Cui, V García-López, Z Wang, Z Luo, D He… - Chemical …, 2024 - ACS Publications
Two-dimensional organic–inorganic (2DOI) van der Waals hybrids (vdWhs) have emerged
as a groundbreaking subclass of layer-stacked (opto-) electronic materials. The …

Oriented growth of thin films of covalent organic frameworks with large single-crystalline domains on the water surface

Z Ou, B Liang, Z Liang, F Tan, X Dong… - Journal of the …, 2022 - ACS Publications
It has been a longstanding challenge to rationally synthesize thin films of organic two-
dimensional (2D) crystals with large single-crystalline domains. Here, we present a general …

Room temperature on-surface synthesis of a vinylene-linked single layer covalent organic framework

FG Fabozzi, N Severin, JP Rabe… - Journal of the American …, 2023 - ACS Publications
Conjugated single-layered two-dimensional covalent organic frameworks are flat and
extended polymer networks with a unique combination of material properties, giving rise to …

On-water surface synthesis of charged two-dimensional polymer single crystals via the irreversible Katritzky reaction

Z Wang, Z Zhang, H Qi, A Ortega-Guerrero, L Wang… - Nature …, 2022 - nature.com
Abstract Two-dimensional polymers (2DPs) and their layer-stacked 2D covalent organic
frameworks (2D COFs) are classes of structurally defined crystalline polymeric materials with …

Recent progress in on-surface synthesis of nanoporous graphene materials

T Qin, T Wang, J Zhu - Communications Chemistry, 2024 - nature.com
Nanoporous graphene (NPG) materials are generated by removing internal degree-3
vertices from graphene and introducing nanopores with specific topological structures …