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Ensemble effect for single-atom, small cluster and nanoparticle catalysts
A large family of heterogeneous catalytic reactions require active sites with more than one
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
Challenges and opportunities in engineering the electronic structure of single-atom catalysts
Controlling the electronic structure of transition-metal single-atom heterogeneous catalysts
(SACs) is crucial to unlocking their full potential. The ability to do this with increasing …
(SACs) is crucial to unlocking their full potential. The ability to do this with increasing …
Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …
crucial to their catalytic performance. However, the complicated surface and interface …
Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles
A high dispersion of the active metal phase of transition metals on oxide supports is
important when designing efficient heterogeneous catalysts. Besides nanoparticles, clusters …
important when designing efficient heterogeneous catalysts. Besides nanoparticles, clusters …
Isolating single and few atoms for enhanced catalysis
Atomically dispersed metal catalysts have triggered great interest in the field of catalysis
owing to their unique features. Isolated single or few metal atoms can be anchored on …
owing to their unique features. Isolated single or few metal atoms can be anchored on …
Single-atom catalysts based on the metal–oxide interaction
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …
Encapsulated metal nanoparticles for catalysis
Metal nanoparticles have drawn great attention in heterogeneous catalysis. One challenge
is that they are easily deactivated by migration-coalescence during the catalysis process …
is that they are easily deactivated by migration-coalescence during the catalysis process …
A stable low-temperature H2-production catalyst by crowding Pt on α-MoC
The water–gas shift (WGS) reaction is an industrially important source of pure hydrogen (H2)
at the expense of carbon monoxide and water,. This reaction is of interest for fuel-cell …
at the expense of carbon monoxide and water,. This reaction is of interest for fuel-cell …
Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …
opportunities for the development of advanced catalysts to address the global challenges in …
Non-carbon-supported single-atom site catalysts for electrocatalysis
Single-atom site catalysts (SACs) have received considerable attention for electrocatalytic
applications, owing to their maximum atom-utilization efficiency, well-identified active …
applications, owing to their maximum atom-utilization efficiency, well-identified active …