O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Heterogeneous catalysis

R Schlögl - Angewandte Chemie International Edition, 2015 - Wiley Online Library
A heterogeneous catalyst is a functional material that continually creates active sites with its
reactants under reaction conditions. These sites change the rates of chemical reactions of …

The surface chemistry of cerium oxide

DR Mullins - Surface Science Reports, 2015 - Elsevier
This review covers the structure of, and chemical reactions on, well-defined cerium oxide
surfaces. Ceria, or mixed oxides containing ceria, are critical components in automotive …

Nanostructured ceria-based materials: synthesis, properties, and applications

C Sun, H Li, L Chen - Energy & Environmental Science, 2012 - pubs.rsc.org
The controllable synthesis of nanostructured CeO2-based materials is an imperative issue
for environment-and energy-related applications. In this review, we present the recent …

Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles

GN Vayssilov, Y Lykhach, A Migani, T Staudt… - Nature materials, 2011 - nature.com
Interactions of metal particles with oxide supports can radically enhance the performance of
supported catalysts. At the microscopic level, the details of such metal–oxide interactions …

Controlling the charge state of supported nanoparticles in catalysis: lessons from model systems

G Pacchioni, HJ Freund - Chemical Society Reviews, 2018 - pubs.rsc.org
Model systems are very important to identify the working principles of real catalysts, and to
develop concepts that can be used in the design of new catalytic materials. In this review we …

Interaction of nanostructured metal overlayers with oxide surfaces

Q Fu, T Wagner - Surface science reports, 2007 - Elsevier
Interactions between metals and oxides are key factors to determine the performance of
metal/oxide heterojunctions, particularly in nanotechnology, where the miniaturization of …

Degree of rate control: how much the energies of intermediates and transition states control rates

C Stegelmann, A Andreasen… - Journal of the American …, 2009 - ACS Publications
For many decades, the concept of a “rate-determining step” has been of central importance
in understanding chemical kinetics in multistep reaction mechanisms and using that …

[LIVRE][B] Spectroscopy in catalysis: an introduction

JW Niemantsverdriet - 2007 - books.google.com
Superbly organized and of great pedagogic value,'Spectroscopy in Catalysis' describes the
most important modern analytical techniques used to investigate catalytic surfaces. These …

Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy

C Lamberti, A Zecchina, E Groppo… - Chemical Society …, 2010 - pubs.rsc.org
This critical review describes the reactivity of heterogeneous catalysts from the point of view
of four simple, but essential for Chemistry, molecules (namely dihydrogen, carbon …