This comprehensive review explores the diverse applications of defective zirconium-based
metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs …

More than 95%(in volume) of all of today's chemical products are manufactured through
catalytic processes, making research into more efficient catalytic materials a thrilling and …

Abstract UiO-66, a water-resistant zirconium-based metal–organic framework (MOF) with
ultra-high porosity, larger surface area and plentiful active sites, has an advantage over …

UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Defect engineering of metal–organic frameworks (MOFs) offers promising opportunities for
tailoring their properties to specific functions and applications. However, determining the …

The targeted incorporation of defects into crystalline matter allows for the manipulation of
many properties and has led to relevant discoveries for optimized and even novel …

Single-atom catalysts are often considered as the ultimate design principle for supported
catalysts, due to their unique geometric and electronic properties and their highly efficient …

Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are
spatially separated in a given solid and, ideally, structurally identical. In this review, the …

Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when
synthesized in the presence of monocarboxylic acid modulators under the most commonly …

Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …