Conspectus Chemists have long pursued harnessing light energy and photoexcitation
processes for synthetic transformations. Ligand-to-metal charge transfer (LMCT) in high …

Alcohols are abundant with versatile structural variety and have ample use as pivotal
functional groups in numerous organic processes. Because of their frequent occurrence in …

The development of effective strategies to forge C–O and C–S bonds in diverse chemical
spaces is of considerable interest in synthetic organic chemistry. Herein we report a versatile …

Transition-metal-catalyzed C (sp3)-H bond functionalization is a useful transformation for the
construction of C–C bonds. A versatile and easy-to-perform protocol in this respect is the C …

We report a dual metal-catalyzed method for the cross-coupling of unprotected alcohols by
exploiting the β-Si effect. This deoxygenative Suzuki-Miyaura reaction tolerates a range of …

Modern medicinal chemists are targeting more complex molecules to address challenging
biological targets, which leads to synthesizing structures with higher sp3 character (Fsp3) to …

Catalytic methods to couple alcohol and alkene feedstocks are highly valuable in synthetic
chemistry. The direct oxidative coupling of primary alcohols and alkenes offers a streamlined …

Herein we report a photoredox/nickel-catalyzed cross-coupling of aryl bromides with 1, 1, 1,
3, 3, 3-hexafluoroisopropanol for the construction of hexafluoroisopropyl aryl ethers. The …

Transition metal catalyzed direct olefination of alkyl heteroarenes with alcohols using
acceptorless dehydrogenative coupling (ADC) reactions and aerobic oxidative olefination …

We present herein a catalytic enantioconvergent diamination of racemic allylic alcohols with
the construction of two C− N bonds and 1, 3‐nonadjacent stereocenters. This iridium/chiral …