Coordinative Chain Transfer and chain shuttling polymerization

R Mundil, C Bravo, N Merle, P Zinck - Chemical Reviews, 2023 - ACS Publications
Coordinative chain transfer polymerization, CCTP, is a degenerative chain transfer
polymerization process that has a wide range of applications. It allows a highly controlled …

Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges

G Zanchin, G Leone - Progress in Polymer Science, 2021 - Elsevier
Polyolefins have dominated materials technology over the last century and remain among
the most used materials, despite environmental problems have emerged and their public …

Recent advances in thermoplastic elastomers from living polymerizations: Macromolecular architectures and supramolecular chemistry

W Wang, W Lu, A Goodwin, H Wang, P Yin… - Progress in polymer …, 2019 - Elsevier
Thermoplastic elastomers (TPEs) have found use in a wide range of applications, such as
adhesives, elastomers, coatings, fibers, and in additive manufacturing techniques such as …

Half-sandwich rare-earth-catalyzed olefin polymerization, carbometalation, and hydroarylation

M Nishiura, F Guo, Z Hou - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus The search for new catalysts for more efficient, selective chemical
transformations and for the synthesis of new functional materials has been a long-standing …

Supported single-site organometallic catalysts for the synthesis of high-performance polyolefins

MM Stalzer, M Delferro, TJ Marks - Catalysis Letters, 2015 - Springer
Single-site organometallic catalysts supported on solid inorganic or organic substrates are
making an important contribution to heterogeneous catalysis. Early and late transition metal …

Biased Lewis Pairs: A General Catalytic Approach to Ether‐Ester Block Copolymers with Unlimited Ordering of Sequences

S Liu, T Bai, K Ni, Y Chen, J Zhao, J Ling… - Angewandte Chemie …, 2019 - Wiley Online Library
Polymerizing epoxides after cyclic esters remains a major challenge, though their block
copolymers have been extensively studied and used for decades. Reported here is a simple …

Development of group 3 catalysts for alternating copolymerization of ethylene and styrene derivatives

S Li, D Liu, Z Wang, D Cui - ACS Catalysis, 2018 - ACS Publications
Alternating copolymers have the clearest and most defined microstructures among
manmade polymers, having been promising building blocks to access synthetic polymers …

Chain shuttling polymerization for cycloolefin block copolymers: from engineering plastics to thermoplastic elastomers

N Qiu, Z Sun, F Yu, K Wang, C Long, Z Dong… - …, 2024 - ACS Publications
Chain shuttling polymerization is a powerful approach for efficiently producing olefin block
copolymers via simple one-pot polymerization. Herein, this method was used to synthesize …

Coordinative chain transfer polymerization of 1-decene in the presence of a Ti-based diamine bis (phenolate) catalyst: A sustainable approach to produce low …

A Hanifpour, N Bahri-Laleh… - Green …, 2020 - pubs.rsc.org
A Ti-based diamine bis (phenolate) catalyst,[Ti {2, 2′-(OC6H2-4, 6-tBu2) 2NHMePhMeNH}
Cl2], was synthesized and fully characterized by elemental analysis and NMR spectroscopy …

Cyclic olefin copolymers containing both linear polyethylene and poly (ethylene-co-norbornene) segments prepared from chain shuttling copolymerization of ethylene …

H Gao, S Chen, B Du, Z Dai, X Lu, K Zhang, L Pan… - Polymer …, 2022 - pubs.rsc.org
Semicrystalline polyethylene (PE) and amorphous poly (ethylene-co-norbornene)
copolymers have been used in a wide variety of applications, especially in packaging. It is a …