Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022‏ - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for develo** high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Structural regulation and support coupling effect of single‐atom catalysts for heterogeneous catalysis

D Liu, Q He, S Ding, L Song - Advanced Energy Materials, 2020‏ - Wiley Online Library
Single atom catalysts (SACs) that integrate the merits of homogeneous and heterogeneous
catalysts have been attracting considerable attention in recent years. The individual metal …

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

CAP Goodwin, F Ortu, D Reta, NF Chilton, DP Mills - Nature, 2017‏ - nature.com
Lanthanides have been investigated extensively for potential applications in quantum
information processing and high-density data storage at the molecular and atomic scale …

High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets

KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018‏ - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

Catalysis by supported single metal atoms

J Liu - Acs Catalysis, 2017‏ - ACS Publications
The recent explosive growth in research on catalysis by supported single metal atoms
proves the scientific interest in this new frontier of heterogeneous catalysis. A supported …

Increasing the Magnetic Blocking Temperature of Single‐Molecule Magnets

V Vieru, S Gómez‐Coca, E Ruiz… - Angewandte …, 2024‏ - Wiley Online Library
The synthesis of single‐molecule magnets (SMMs), magnetic complexes capable of
retaining magnetization blocking for a long time at elevated temperatures, has been a major …

Molecular magnetism of lanthanide: Advances and perspectives

Z Zhu, M Guo, XL Li, J Tang - Coordination Chemistry Reviews, 2019‏ - Elsevier
The discovery of the first example of lanthanide-based single molecule magnets (Ln-SMMs),
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …

[HTML][HTML] Hexagonal boron nitride monolayers on metal supports: Versatile templates for atoms, molecules and nanostructures

W Auwärter - Surface Science Reports, 2019‏ - Elsevier
Hexagonal boron nitride (hBN) monolayers have attracted considerable interest as
atomically thin sp 2-hybridized sheets that are readily synthesized on various metal …

Reading and writing single-atom magnets

FD Natterer, K Yang, W Paul, P Willke, T Choi, T Greber… - Nature, 2017‏ - nature.com
The single-atom bit represents the ultimate limit of the classical approach to high-density
magnetic storage media. So far, the smallest individually addressable bistable magnetic bits …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016‏ - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …