Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

Magnetic materials based on heterometallic Cr II/III–Ln III complexes

P Shukla, S Das, P Bag, A Dey - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Accommodating disparate spin centres within a single ensemble is a valuable synthetic
strategy to obtain interesting molecular magnetic materials. 3d–4f heterometallic complexes …

Opening magnetic hysteresis by axial ferromagnetic coupling: from mono‐decker to double‐decker metallacrown

J Wang, QW Li, SG Wu, YC Chen, RC Wan… - Angewandte …, 2021 - Wiley Online Library
Combining Ising‐type magnetic anisotropy with collinear magnetic interactions in single‐
molecule magnets (SMMs) is a significant synthetic challenge. Herein we report a Dy [15 …

Recent advances in 3d-4f magnetic complexes with several types of non-carboxylate organic ligands

HS Wang, K Zhang, Y Song, ZQ Pan - Inorganica Chimica Acta, 2021 - Elsevier
Since 1993, single molecule magnets (SMMs) have received a wide attention for their
potential applications in high-density information storage device, quantum computer and …

Realization of toroidal magnetic moments in heterometallic 3d–4f metallocycles

J Wu, XL Li, M Guo, L Zhao, YQ Zhang… - Chemical …, 2018 - pubs.rsc.org
Realization of toroidal magnetic moments in heterometallic 3d–4f metallocycles - Chemical
Communications (RSC Publishing) DOI:10.1039/C7CC09391H Royal Society of Chemistry …

Suppression of zero-field quantum tunneling of magnetization by a fluorido bridge for a" very hard" 3d-4f single-molecule magnet

BK Ling, YQ Zhai, PB **, HF Ding, XF Zhang, Y Lv… - Matter, 2022 - cell.com
Single-molecule magnets (SMMs) have been proposed for ultra-high-density information
storage due to prolonged relaxation times below blocking temperature (TB). However, many …

Inorganic Approach to Stabilizing Nanoscale Toroidicity in a Tetraicosanuclear Fe18Dy6 Single Molecule Magnet

H Kaemmerer, A Baniodeh, Y Peng… - Journal of the …, 2020 - ACS Publications
Cyclic coordination clusters (CCCs) are proving to provide an extra dimension in terms of
exotic magnetic behavior as a result of their finite but cyclized chain structures. The Fe18Dy6 …

Molecular nanomagnets with competing interactions as optimal units for qudit-based quantum computation

M Chizzini, L Crippa, A Chiesa, F Tacchino… - Physical Review …, 2022 - APS
Quantum systems displaying many accessible levels could be very powerful units of
forthcoming quantum computing architectures. Indeed, the large number of available states …

Recent advance in heterometallic nanomagnets based on TMxLn4− x cubane subunits

J Wang, M Feng, MN Akhtar, ML Tong - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract 3d-4f cubane-like complexes exhibit unique structural pattern, thus become a
fascinating subclass of 3d-4f complexes. In this review, we first present the structural …

Slow magnetic relaxation in lanthanoid crown ether complexes: interplay of Raman and anomalous phonon bottleneck processes

E Rousset, M Piccardo, ME Boulon… - … A European Journal, 2018 - Wiley Online Library
The combination of lanthanoid nitrates with 18‐crown‐6 (18‐c‐6) and tetrahalocatecholate
(X4Cat2−, X= Cl, Br) ligands has afforded two compound series [Ln (18‐c‐6)(X4Cat)(NO3)]⋅ …