Enantioselective radical reactions using chiral catalysts
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
Transition-metal-catalyzed cross-couplings through carbene migratory insertion
Y **a, D Qiu, J Wang - Chemical reviews, 2017 - ACS Publications
Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …
indispensable tools in modern organic synthesis. One of the major research goals in cross …
Recent advances in the preparation and application of allylboron species in organic synthesis
C Diner, KJ Szabo - Journal of the American Chemical Society, 2017 - ACS Publications
Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …
Recent advances in catalytic asymmetric synthesis of allenes
WD Chu, Y Zhang, J Wang - Catalysis Science & Technology, 2017 - pubs.rsc.org
Allene moieties with axial chirality are featured in many natural products with biological
activities. They also serve as unique building blocks in organic synthesis and as chiral …
activities. They also serve as unique building blocks in organic synthesis and as chiral …
1,n‐Hydrogen‐Atom Transfer (HAT) Reactions in Which n≠5: An Updated Inventory
Hydrogen‐atom transfer (HAT) counts amongst the most widely investigated routes to
carbon‐centered radicals. Intramolecular processes involving 1, 5‐HAT are widespread to …
carbon‐centered radicals. Intramolecular processes involving 1, 5‐HAT are widespread to …
Enantioselective synthesis of trisubstituted allenes via Cu (I)-catalyzed coupling of diazoalkanes with terminal alkynes
A highly enantioselective synthesis of trisubstituted allenes has been achieved through Cu
(I)-catalyzed cross-coupling of aryldiazoalkanes and terminal alkynes with chiral …
(I)-catalyzed cross-coupling of aryldiazoalkanes and terminal alkynes with chiral …
Concerted reactions that produce diradicals and zwitterions: electronic, steric, conformational, and kinetic control of cycloaromatization processes
The broad utility of cyclic structures accounts for the key roles that cycle-forming reactions
play in synthetic designs. Most of these reactions can be classified as either a cyclization of …
play in synthetic designs. Most of these reactions can be classified as either a cyclization of …
Axial-to-central chirality transfer in cyclization processes
D Campolo, S Gastaldi, C Roussel… - Chemical Society …, 2013 - pubs.rsc.org
Substrates, bearing axial chirality, can cyclize intra-or inter-molecularly with concomitant
transfer of axial-to-central chirality to produce at least one stereocenter. In order to satisfy a …
transfer of axial-to-central chirality to produce at least one stereocenter. In order to satisfy a …
CuI-Catalyzed Cross-Coupling of N-Tosylhydrazones with Terminal Alkynes: Synthesis of 1,3-Disubstituted Allenes
ML Hossain, F Ye, Y Zhang, J Wang - The Journal of Organic …, 2013 - ACS Publications
A CuI-catalyzed synthesis of 1, 3-disubstituted allenes from 1-alkynes by the reaction with
various N-tosylhydrazones has been developed. This method, which uses readily available …
various N-tosylhydrazones has been developed. This method, which uses readily available …
(Hetero) aromatics from dienynes, enediynes and enyne–allenes
The construction of aromatic rings has become a key objective for organic chemists. While
several strategies have been developed for the functionalization of pre-formed aromatic …
several strategies have been developed for the functionalization of pre-formed aromatic …