The effect of coordination environment on the activity and selectivity of single-atom catalysts

Y Zhang, J Yang, R Ge, J Zhang, JM Cairney… - Coordination Chemistry …, 2022 - Elsevier
Traditional heterogeneous catalysts with noble metals as active sites only have surface-
active substances involved in the catalytic reactions, which greatly reduces the material …

Catalysis by clusters with precise numbers of atoms

EC Tyo, S Vajda - Nature nanotechnology, 2015 - nature.com
Clusters that contain only a small number of atoms can exhibit unique and often unexpected
properties. The clusters are of particular interest in catalysis because they can act as …

Increasing oxide reducibility: the role of metal/oxide interfaces in the formation of oxygen vacancies

A Ruiz Puigdollers, P Schlexer, S Tosoni… - Acs …, 2017 - ACS Publications
Reducibility is an essential characteristic of oxide catalysts in oxidation reactions following
the Mars–van Krevelen mechanism. A typical descriptor of the reducibility of an oxide is the …

Au Sub‐Nanoclusters on TiO2 toward Highly Efficient and Selective Electrocatalyst for N2 Conversion to NH3 at Ambient Conditions

MM Shi, D Bao, BR Wulan, YH Li, YF Zhang… - Advanced …, 2017 - Wiley Online Library
As the N N bond in N2 is one of the strongest bonds in chemistry, the fixation of N2 to
ammonia is a kinetically complex and energetically challenging reaction and, up to now, its …

Towards bridging thermo/electrocatalytic CO oxidation: from nanoparticles to single atoms

K Wei, X Wang, J Ge - Chemical Society Reviews, 2024 - pubs.rsc.org
Proton exchange membrane fuel cells (PEMFCs), as a feasible alternative to replace the
traditional fossil fuel-based energy converter, contribute significantly to the global …

Ultrastable single-atom gold catalysts with strong covalent metal-support interaction (CMSI)

B Qiao, JX Liang, A Wang, CQ Xu, J Li, T Zhang, JJ Liu - Nano Research, 2015 - Springer
Supported noble metal nanoparticles (including nanoclusters) are widely used in many
industrial catalytic processes. While the finely dispersed nanostructures are highly active …

Stabilization of single metal atoms on graphitic carbon nitride

Z Chen, S Mitchell, E Vorobyeva… - Advanced Functional …, 2017 - Wiley Online Library
Graphitic carbon nitride (g‐C3N4) exhibits unique properties as a support for single‐atom
heterogeneous catalysts (SAHCs). Understanding how the synthesis method, carrier …

Single-atom catalysis of CO oxidation using Pt1/FeOx

B Qiao, A Wang, X Yang, LF Allard, Z Jiang, Y Cui… - Nature …, 2011 - nature.com
Platinum-based heterogeneous catalysts are critical to many important commercial chemical
processes, but their efficiency is extremely low on a per metal atom basis, because only the …

Dynamic formation of single-atom catalytic active sites on ceria-supported gold nanoparticles

YG Wang, D Mei, VA Glezakou, J Li… - Nature …, 2015 - nature.com
Catalysis by gold supported on reducible oxides has been extensively studied, yet issues
such as the nature of the catalytic site and the role of the reducible support remain fiercely …

Recent progress in noble metal nanocluster and single atom electrocatalysts for the hydrogen evolution reaction

J Cai, R Javed, D Ye, H Zhao, J Zhang - Journal of Materials Chemistry …, 2020 - pubs.rsc.org
Hydrogen, a renewable and clean energy carrier, is the best alternative to fossil fuels.
Hydrogen evolution from water electrolysis using renewable electrical energy is quite …