Carbon monoxide was discovered and identified in the 18th century. Since the first
applications in industry 80 years ago, academic and industrial laboratories have broadly …

Transition metal-catalysed carbene-and nitrene transfer to the C1-building blocks carbon
monoxide and isocyanides provides heteroallenes (ie ketenes, isocyanates, ketenimines …

In the last decade there have been numerous advances in the area of rhodium-catalyzed
hydroformylation, such as highly selective catalysts of industrial importance, new insights …

Hydroformylation is one of the largest industrially homogeneous processes that strongly
relies on catalysts with phosphine ligands such as the Wilkinson's catalyst …

A series of diphosphine ligand constructed porous polymers with stable and flexible
frameworks have been successfully synthesized under the solvothermal conditions from …

The hydricity Δ G° H–of a metal hydride is an important parameter for describing the
reactivity of such complexes. Here, we compile a comprehensive data set consisting of 51 …

The metal‐catalysed hydrofunctionalisation of alkenes and alkynes provides a convenient
and atom‐economic route to diversely functionalised products with control of regio‐, chemo …

Transition metal-catalyzed hydrocarbonations of unsaturated substrates have emerged as
powerful synthetic tools for increasing molecular complexity in an atom-economical manner …

Terminal alkenes are readily available functional groups which appear in α‐olefins
produced by the chemical industry, and they appear in the products of many contemporary …

The metal-catalyzed isomerization–hydroformylation tandem reaction is of great importance
for the production of linear aldehydes starting from internal olefins, but also, the shift of the …