Aqueous alteration of silicate glass: state of knowledge and perspectives

S Gin, JM Delaye, F Angeli, S Schuller - npj Materials Degradation, 2021 - nature.com
The question of silicate glass chemical durability is at the heart of many industrial and
environmental issues, with certain glasses, such as bioglasses, needing to transform rapidly …

Forty years of durability assessment of nuclear waste glass by standard methods

CL Thorpe, JJ Neeway, CI Pearce, RJ Hand… - npj Materials …, 2021 - nature.com
Standard methods to assess the durability of vitrified radioactive waste were first developed
in the 1980's and, over the last 40 years, have evolved to yield a range of responses …

[HTML][HTML] Solving the retention time repeatability problem of hydrophilic interaction liquid chromatography

K Serafimov, C Knappe, F Li, A Sievers-Engler… - … of Chromatography A, 2024 - Elsevier
Hydrophilic interaction (liquid) chromatography (HILIC) has become the first choice LC
mode for the separation of hydrophilic analytes. Numerous studies reported the poor …

Deciphering the non-linear impact of Al on chemical durability of silicate glass

K Damodaran, JM Delaye, AG Kalinichev, S Gin - Acta Materialia, 2022 - Elsevier
The role of Al in aluminosilicate glasses remains somewhat a mystery: at low concentrations,
it increases the resistance to hydrolysis of the glass, whereas at high concentrations an …

On the effect of Al on alumino-borosilicate glass chemical durability

K Damodaran, S Gin, S Narayanasamy… - npj Materials …, 2023 - nature.com
The chemical durability of borosilicate glass used to confine nuclear wastes is known to vary
nonlinearly with their composition, making glass dissolution rate predictions difficult. Here …

Effect of structural disorder induced by external irradiation with heavy ions on the alteration of a four oxide borosilicate glass

S Gin, M Taron, H Arena, JM Delaye - npj Materials Degradation, 2024 - nature.com
The irradiation of glass by heavy ions induces structural damage, generally leading to a
decrease in its chemical durability whose amplitude strongly depends on the glass chemical …

Influence of radiation on borosilicate glass leaching behaviors

K Qin, B Zhang, Z **, Y Wang, Y Pan, Y Sun… - npj Materials …, 2024 - nature.com
Vitrification is widely recognized as a promising method for the geological disposal of high-
level radioactive waste (HLW) worldwide. To ensure the safe disposal of radioactive waste …

Insights into the mechanism and kinetics of dissolution of aluminoborosilicate glasses in acidic media: Impact of high ionic field strength cations

Q Qin, N Stone-Weiss, T Zhao, P Mukherjee, J Ren… - Acta Materialia, 2023 - Elsevier
Achieving thinner and higher performance display/substrate glasses and transparent glass-
ceramics with tunable properties requires a precise control of acid-etching process, thus …

Comparative study of the structure and durability of commercial silicate glasses for food consumption and cosmetic packaging

L Brunswic, F Angeli, T Charpentier, S Gin… - npj Materials …, 2024 - nature.com
Four commercial glass compositions were investigated to understand their mechanisms of
alteration in light of the current and future regulations on food contact materials. Lead crystal …

Atomic insights into the events governing the borosilicate glass–water interface

H Jabraoui, T Charpentier, S Gin… - The Journal of …, 2021 - ACS Publications
An atomistic understanding of the mechanisms that govern the borosilicate glass–water
interface is highly needed to obtain initial assessments of the phenomena occurring during …