The area of direct asymmetric functionalization of inert C–H bonds has attracted
considerable attention in recent years. To realize this type of challenging but promising …

Accessing hindered amines, particularly primary amines α to a fully substituted carbon
center, is synthetically challenging. We report an electrochemical method to access such …

An efficient Rh (III)-catalyzed stepwise ortho allylation of N-methoxybenzamides 1 with
polysubstituted allenes is reported. This C–H functionalization involving allenes is …

Dreifache Selektivität: Hochsubstituierte Indenylamine werden mit hohen
Enantioselektivitäten durch formale [3+ 2]‐Additionen von Arylketiminen an interne Alkine …

A Rh (III)-catalyzed oC–H bond functionalization-based allenylation reaction of
allenylsilanes 2 with N-methoxybenzamides 1 affords poly-substituted allenylsilanes with a …

The vast occurrence of optically active amines in natural products and compounds with
biological activity has prompted numerous efforts toward their synthesis.[1] Although a broad …

In this review, recent advances in the utilization of two classes of rhodium catalysts–namely
rhodium (I) and rhodium (III)–in complexation with chiral cyclopentadienyl and phosphorus …

The divergence between Rh (III)-catalyzed C–H activation/cycloaddition of phenyl-and 2-
furanyl-containing benzamides with methylenecyclopropanes (MCP) was studied by DFT …

Under the catalysis of a rhodium (III) complex, the cyclization of 2, 3-allenols was most
probably initiated with the C H bond functionalization of N-methoxybenzamides using the …

The direct functionalization of non-activated C–H bonds, especially in an enantioselective
manner, requires metal catalysts equipped with ligands with specifically designed …