Recent developments on the transformation of CO 2 utilising ligand cooperation and related strategies
A portfolio of value-added chemicals, fuels and building block compounds can be
envisioned from CO2 on an industrial scale. The high kinetic and thermodynamic stabilities …
envisioned from CO2 on an industrial scale. The high kinetic and thermodynamic stabilities …
Cooperative dihydrogen activation with unsupported uranium–metal bonds and characterization of a terminal U (iv) hydride
RJ Ward, P Rungthanaphatsophon, P Huang… - Chemical …, 2023 - pubs.rsc.org
Cooperative chemistry between two or more metal centres can show enhanced reactivity
compared to the monometallic fragments. Given the paucity of actinide–metal bonds …
compared to the monometallic fragments. Given the paucity of actinide–metal bonds …
Cooperative C–H Bond Activation by a Low-Spin d6 Iron–Aluminum Complex
The reactions of transition metal complexes underpin numerous synthetic processes and
catalytic transformations. Typically, this reactivity involves the participation of empty and …
catalytic transformations. Typically, this reactivity involves the participation of empty and …
Polarized Au (I)/Rh (I) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation
The combination of molecular metallic fragments of contrasting Lewis character offers many
possibilities for cooperative bond activation and for the disclosure of unusual reactivity. Here …
possibilities for cooperative bond activation and for the disclosure of unusual reactivity. Here …
Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis
The incorporation of boron functionalities into transition-metal catalysts has become a
promising strategy to improve catalytic performance, although their synthesis typically entails …
promising strategy to improve catalytic performance, although their synthesis typically entails …
Alkane Elimination Preparation of Heterobimetallic MoAl Tetranuclear and Binuclear Complexes Promoting THF Ring Opening
We report a straightforward alkane elimination strategy to prepare well-defined
heterobimetallic Al/Mo species. Notably, the reaction of the monohydride complex of …
heterobimetallic Al/Mo species. Notably, the reaction of the monohydride complex of …
A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
N Hidalgo, F De La Cruz-Martinez, MT Martín… - Chemical …, 2022 - pubs.rsc.org
A series of Au (I)/Pt (0) combinations that behave as bimetallic frustrated Lewis pairs
activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines …
activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines …
Tweaking the bridge in metallocene Zr (IV)/W (IV) bimetallic hydrides
Zirconocene cations react with Cp2WH2 affording the bimetallic [Cp2Zr (μ-H)(μ–η1: η5-
C5H4) WHCp]+ bridging hydride 1 (Cp= cyclopentadienyl anion, C5H5−) via σ-bond …
C5H4) WHCp]+ bridging hydride 1 (Cp= cyclopentadienyl anion, C5H5−) via σ-bond …
Chemical Transformations in Heterobimetallic Complexes Facilitated by the Second Coordination Sphere
R Malcolm Charles III, TP Brewster - Modes of Cooperative Effects in …, 2023 - Springer
This chapter is dedicated to heterobimetallic complexes in which the two metal centers are
not directly bound. Complexes are described in which the second metal resides in the …
not directly bound. Complexes are described in which the second metal resides in the …
A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
N Hidalgo Campos, F Cruz-Martínez, M Martín… - 2022 - digital.csic.es
A series of Au (I)/Pt (0) combinations that behave as bimetallic frustrated Lewis pairs
activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines …
activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines …