The recent development of efficient Earth-abundant transition-metal nanocatalysts

D Wang, D Astruc - Chemical Society Reviews, 2017 - pubs.rsc.org
Whereas noble metal compounds have long been central in catalysis, Earth-abundant metal-
based catalysts have in the same time remained undeveloped. Yet the efficacy of Earth …

Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and …

JA Rodriguez, DC Grinter, Z Liu… - Chemical Society …, 2017 - pubs.rsc.org
Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for
studying fundamental phenomena linked to the operation of technical catalysts. In the last …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Oxygen and Chlorine Dual Vacancies Enable Photocatalytic O2 Dissociation into Monatomic Reactive Oxygen on BiOCl for Refractory Aromatic Pollutant Removal

Z Yang, Y Shi, H Li, C Mao, X Wang, X Liu… - Environmental …, 2022 - ACS Publications
Room-temperature molecular oxygen (O2) dissociation is challenging toward chemical
reactions due to its triplet ground-state and spin-forbidden characteristic. Herein, we …

An amorphous noble‐metal‐free electrocatalyst that enables nitrogen fixation under ambient conditions

C Lv, C Yan, G Chen, Y Ding, J Sun… - Angewandte …, 2018 - Wiley Online Library
N2 fixation by the electrocatalytic nitrogen reduction reaction (NRR) under ambient
conditions is regarded as a potential approach to achieve NH3 production, which still …

Scalable synthesis of Cu clusters for remarkable selectivity control of intermediates in consecutive hydrogenation

D Yao, Y Wang, Y Li, A Li, Z Zhen, J Lv, F Sun… - Nature …, 2023 - nature.com
Subnanometric Cu clusters that contain only a small number of atoms exhibit unique and,
often, unexpected catalytic behaviors compared with Cu nanoparticles and single atoms …

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2

J Graciani, K Mudiyanselage, F Xu, AE Baber, J Evans… - Science, 2014 - science.org
The transformation of CO2 into alcohols or other hydrocarbon compounds is challenging
because of the difficulties associated with the chemical activation of CO2 by heterogeneous …

Water-promoted interfacial pathways in methane oxidation to methanol on a CeO2-Cu2O catalyst

Z Liu, E Huang, I Orozco, W Liao, RM Palomino, N Rui… - Science, 2020 - science.org
Highly selective oxidation of methane to methanol has long been challenging in catalysis.
Here, we reveal key steps for the promotion of this reaction by water when tuning the …

Active Cu0–Cuσ+ Sites for the Hydrogenation of Carbon–Oxygen Bonds over Cu/CeO2 Catalysts

A Li, D Yao, Y Yang, W Yang, Z Li, J Lv, S Huang… - ACS …, 2022 - ACS Publications
CeO2-supported copper species have been reported as an active catalyst for the
hydrogenation of carbon–oxygen bonds (CO, CO2, furfural, esters, etc.). However, the …

Mechanistic Insight into the Promotion of the Low-Temperature NH3-Selective Catalytic Reduction Activity over MnxCe1–xOy Catalysts: A Combined …

M Li, M Gao, G He, Y Yu, H He - Environmental Science & …, 2023 - ACS Publications
CeO2 has attracted much attention in the field of selective catalytic reduction of NO with NH3
(NH3-SCR). However, poor low-temperature activity and a narrow operation window restrict …