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Ruthenium (II) polypyridyl complexes and DNA—from structural probes to cellular imaging and therapeutics
In the last few decades, coordination complexes based on d6 metal centres and polypyridyl
ligand architectures been developed as structure-and site-specific reversible DNA binding …
ligand architectures been developed as structure-and site-specific reversible DNA binding …
[HTML][HTML] Microwave-assisted synthesis: Can transition metal complexes take advantage of this “Green” method?
E Gabano, M Ravera - Molecules, 2022 - mdpi.com
Microwave-assisted synthesis is considered environmental-friendly and, therefore, in
agreement with the principles of green chemistry. This form of energy has been employed …
agreement with the principles of green chemistry. This form of energy has been employed …
[KSIĄŻKA][B] Microwave heating as a tool for sustainable chemistry
NE Leadbeater - 2010 - taylorfrancis.com
Shorter reaction times, higher product yields, and enhanced selectivity are some of the
advantages microwave heating has over conventional methods, causing its use to transition …
advantages microwave heating has over conventional methods, causing its use to transition …
Optically pure, water-stable metallo-helical 'flexicate'assemblies with antibiotic activity
SE Howson, A Bolhuis, V Brabec, GJ Clarkson… - Nature …, 2012 - nature.com
The helicates—chiral assemblies of two or more metal atoms linked by short or relatively
rigid multidentate organic ligands—may be regarded as non-peptide mimetics of α-helices …
rigid multidentate organic ligands—may be regarded as non-peptide mimetics of α-helices …
Luminescent, enantiopure, phenylatopyridine iridium-based coordination capsules
The first molecular capsule based on an [Ir (ppy) 2]+ unit (ppy= 2-phenylatopyridine) has
been prepared. Following the development of a method to resolve rac-[(Ir (ppy) 2Cl) 2] into …
been prepared. Following the development of a method to resolve rac-[(Ir (ppy) 2Cl) 2] into …
Alternative technologies that facilitate access to discrete metal complexes
A Beillard, X Bantreil, TX Métro, J Martinez… - Chemical …, 2019 - ACS Publications
Organometallic complexes: these two words jump to the mind of the chemist and are directly
associated with their utility in catalysis or as a pharmaceutical. Nevertheless, to be able to …
associated with their utility in catalysis or as a pharmaceutical. Nevertheless, to be able to …
Exciton coupling in coordination compounds
This Perspective reviews the impact of exciton coupling on the spectroscopic properties of
coordination compounds. Exciton coupling features arise in electronic absorption and …
coordination compounds. Exciton coupling features arise in electronic absorption and …
Structural design principles for self-assembled coordination polygons and polyhedra
NJ Young, BP Hay - Chemical Communications, 2013 - pubs.rsc.org
Strategies for the design of ligands that combine with metal ions to form high-symmetry
coordination assemblies are reviewed. Evaluation of crystal structure evidence reveals that …
coordination assemblies are reviewed. Evaluation of crystal structure evidence reveals that …
Controlling the Transmission of Stereochemical Information through Space in Terphenyl-Edged Fe4L6 Cages
A series of terphenyl-edged Fe4L6 cages were synthesized from substituted 4, 4′′-
diamino-p-terphenyls, 2-formylpyridine, and iron (II). For the parent diaminoterphenyl, all …
diamino-p-terphenyls, 2-formylpyridine, and iron (II). For the parent diaminoterphenyl, all …
Subcomponent Self-Assembly and Guest-Binding Properties of Face-Capped Fe4L4 8+ Capsules
A general method for preparing Fe4L4 face-capped tetrahedral cages through
subcomponent self-assembly was developed and has been demonstrated using four …
subcomponent self-assembly was developed and has been demonstrated using four …