Ruthenium (II) polypyridyl complexes and DNA—from structural probes to cellular imaging and therapeutics

MR Gill, JA Thomas - Chemical Society Reviews, 2012 - pubs.rsc.org
In the last few decades, coordination complexes based on d6 metal centres and polypyridyl
ligand architectures been developed as structure-and site-specific reversible DNA binding …

[HTML][HTML] Microwave-assisted synthesis: Can transition metal complexes take advantage of this “Green” method?

E Gabano, M Ravera - Molecules, 2022 - mdpi.com
Microwave-assisted synthesis is considered environmental-friendly and, therefore, in
agreement with the principles of green chemistry. This form of energy has been employed …

[KSIĄŻKA][B] Microwave heating as a tool for sustainable chemistry

NE Leadbeater - 2010 - taylorfrancis.com
Shorter reaction times, higher product yields, and enhanced selectivity are some of the
advantages microwave heating has over conventional methods, causing its use to transition …

Optically pure, water-stable metallo-helical 'flexicate'assemblies with antibiotic activity

SE Howson, A Bolhuis, V Brabec, GJ Clarkson… - Nature …, 2012 - nature.com
The helicates—chiral assemblies of two or more metal atoms linked by short or relatively
rigid multidentate organic ligands—may be regarded as non-peptide mimetics of α-helices …

Luminescent, enantiopure, phenylatopyridine iridium-based coordination capsules

O Chepelin, J Ujma, X Wu, AMZ Slawin… - Journal of the …, 2012 - ACS Publications
The first molecular capsule based on an [Ir (ppy) 2]+ unit (ppy= 2-phenylatopyridine) has
been prepared. Following the development of a method to resolve rac-[(Ir (ppy) 2Cl) 2] into …

Alternative technologies that facilitate access to discrete metal complexes

A Beillard, X Bantreil, TX Métro, J Martinez… - Chemical …, 2019 - ACS Publications
Organometallic complexes: these two words jump to the mind of the chemist and are directly
associated with their utility in catalysis or as a pharmaceutical. Nevertheless, to be able to …

Exciton coupling in coordination compounds

SG Telfer, TM McLean, MR Waterland - Dalton Transactions, 2011 - pubs.rsc.org
This Perspective reviews the impact of exciton coupling on the spectroscopic properties of
coordination compounds. Exciton coupling features arise in electronic absorption and …

Structural design principles for self-assembled coordination polygons and polyhedra

NJ Young, BP Hay - Chemical Communications, 2013 - pubs.rsc.org
Strategies for the design of ligands that combine with metal ions to form high-symmetry
coordination assemblies are reviewed. Evaluation of crystal structure evidence reveals that …

Controlling the Transmission of Stereochemical Information through Space in Terphenyl-Edged Fe4L6 Cages

W Meng, JK Clegg, JD Thoburn… - Journal of the American …, 2011 - ACS Publications
A series of terphenyl-edged Fe4L6 cages were synthesized from substituted 4, 4′′-
diamino-p-terphenyls, 2-formylpyridine, and iron (II). For the parent diaminoterphenyl, all …

Subcomponent Self-Assembly and Guest-Binding Properties of Face-Capped Fe4L4 8+ Capsules

RA Bilbeisi, JK Clegg, N Elgrishi… - Journal of the …, 2011 - ACS Publications
A general method for preparing Fe4L4 face-capped tetrahedral cages through
subcomponent self-assembly was developed and has been demonstrated using four …