Recent advances in polyoxometalate-catalyzed reactions

SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Deep oxidative desulfurization of gas oil by iron(III)-substituted polyoxometalate immobilized on nickel(II) oxide, ((nC4H9)4N)4H[PW11FeO39]@NiO, as an …

MA Rezvani, K Ghasemi, HH Ardeshiri… - Scientific Reports, 2023 - nature.com
Sulfur compounds are among the most unfavorable constituents of petroleum derivatives, so
stringent regulations have been established to curb their atmospheric emissions. In this …

Synthesis and characterization of PWMn/NiO/PAN nanosphere composite with superior catalytic activity for oxidative desulfurization of real fuel

MA Rezvani, OF Miri - Chemical Engineering Journal, 2019 - Elsevier
A new organic-inorganic hybrid material (PWMn/NiO/PAN) was successfully synthesized
based on cesium salt of mono Mn (II)-substituted phosphotungstate Cs 5 PW 11 MnO 39 …

Modified Mn substituted POMs: Synthetic strategies, structural diversity to applications

A Patel, R Sadasivan - Progress in Materials Science, 2021 - Elsevier
A discrete class of metal–oxygen clusters, Polyoxometalates (POMs) have received
tremendous attention for their convenient shapes, sizes, compositions and structural …

Deep catalytic oxidative desulfurization process catalyzed by TBA-PWFe@ NiO@ BNT composite material as an efficient and recyclable phase-transfer nanocatalyst

MA Rezvani, P Afshari, M Aghmasheh - Materials Chemistry and Physics, 2021 - Elsevier
The production of high-quality fuel with substantially lowered sulfur level has attracted a
great deal of attention in recent years. Develo** high-performance and recyclable …

Post‐synthetic Metalation on the Ionic TiO2 Surface to Enhance Metal‐CO2 Interaction During Photochemical CO2 Reduction

L Mallick, K Samanta… - Chemistry–A European …, 2024 - Wiley Online Library
During the photochemical CO2 reduction reaction, CO2 adsorption on the catalyst's surface
is a crucial step where the binding mode of the [metal‐CO2] adduct directs the product …

Mono Mn (II)-substituted phosphotungstate@ modified graphene oxide as a high-performance nanocatalyst for oxidative demercaptanization of gasoline

MA Rezvani, ZS Aghbolagh, HH Monfared… - Journal of industrial and …, 2017 - Elsevier
In this study, the removal of hazardous sulfur compounds from gasoline was provided based
on catalytic oxidation demercaptanization technique. The cesium salt of mono Mn (II) …

Selective oxidation of methanol to dimethoxymethane over iron and vanadate modified phosphotungstate

S Zou, H Wang, S Li, B Lu, J Zhao, Q Cai - Applied Surface Science, 2022 - Elsevier
Iron and vanadate modified phosphotungstate was fabricated by Fe salt and vanadate
incorporating into H 3 PW 12 O 40. Its morphology, composition and structure were …

Synthesis and characterization of new nano organic-inorganic hybrid (TBA) 4PW11Fe@ TiO2@ PVA as a promising phase-transfer catalyst for oxidative …

MA Rezvani, ZN Oghoulbeyk, S Khandan, HG Mazzei - Polyhedron, 2020 - Elsevier
In this work, an efficient oxidative desulfurization (ODS) process of real gas oil and model
oils was introduced using (TBA) 4 PW 11 Fe@ TiO 2@ PVA phase-transfer catalyst. The …

Catalytic oxidation of styrene and its reaction mechanism consideration over bimetal modified phosphotungstates

Y Zhang, H Wang, S Li, B Lu, J Zhao, Q Cai - Molecular Catalysis, 2021 - Elsevier
Cobalt and nickel modified phospotungstates (CoNiPW) were fabricated via the reaction of
H 3 PW 12 O 40• 6• 5H 2 O (PW) with Co (NO 3) 2• 6H 2 O and NiCl• 6H 2 O, followed by …