Metal-mediated reductive hydrodehalogenation of organic halides

F Alonso, IP Beletskaya, M Yus - Chemical reviews, 2002 - ACS Publications
Organic halides are very important and versatile compounds with many applications as
starting materials, solvents, reagents, and intermediates in synthetic organic chemistry. 1 …

The destruction of organic pollutants under mild reaction conditions: A review

DF Laine, IF Cheng - Microchemical journal, 2007 - Elsevier
A survey of the literature covering the destruction of organic pollutants accomplished under
mild reaction conditions is presented. Technologies presented are segregated according to …

Reductive elimination of chlorinated ethylenes by zero-valent metals

AL Roberts, LA Totten, WA Arnold… - Environmental …, 1996 - ACS Publications
Reductive dehalogenation reactions are generally divided into two categories (1-3):
hydrogenolysis (replacement of a halogen by a hydrogen) and reductive elimination (in …

Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 1. Pyrite and magnetite

W Lee, B Batchelor - Environmental Science & Technology, 2002 - ACS Publications
Abiotic reductive dechlorination of chlorinated ethylenes (tetrachloroethylene (PCE),
trichloroethylene (TCE), cis-dichloroethylene (cis-DCE), and vinyl chloride (VC)) by pyrite …

Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 2. Green rust

W Lee, B Batchelor - Environmental Science & Technology, 2002 - ACS Publications
Abiotic reductive dechlorination of chlorinated ethylenes by the sulfate form of green rust
(GRSO4) was examined in batch reactors. Dechlorination kinetics were described by a …

Reductive defluorination of branched per-and polyfluoroalkyl substances with cobalt complex catalysts

J Liu, DJ Van Hoomissen, T Liu, A Maizel… - … & Technology Letters, 2018 - ACS Publications
This study investigates structure–reactivity relationships within branched per-and
polyfluoroalkyl substances (PFASs) undergoing cobalt-catalyzed reductive defluorination …

Corrinoid-mediated reduction of tetrachloroethene, trichloroethene, and trichlorofluoroethene in homogeneous aqueous solution: Reaction kinetics and reaction …

G Glod, W Angst, C Holliger… - … Science & Technology, 1996 - ACS Publications
It is shown that in homogeneous aqueous solution containing titanium (III) citrate or titanium
(III)− NTA as bulk electron donor, cobalamin, cobinamide, and cobamide are effective …

Reductive Dechlorination of Tetrachloroethylene and Trichloroethylene Catalyzed by Vitamin B12 in Homogeneous and Heterogeneous Systems

DR Burris, CA Delcomyn, MH Smith… - … Science & Technology, 1996 - ACS Publications
The reduction of tetrachloroethylene (PCE) and trichloroethylene (TCE) catalyzed by vitamin
B12 was examined in homogeneous and heterogeneous (B12 bound to agarose) batch …

Utilization of cathodic hydrogen as electron donor for chloroform cometabolism by a mixed, methanogenic culture

LJ Weathers, GF Parkin, PJ Alvarez - Environmental science & …, 1997 - ACS Publications
Currently there is considerable interest in using elemental iron (Fe0) for treatment of highly
chlorinated organic compounds. Early studies found little microbiological contribution to …

Non‐native Intramolecular Radical Cyclization Catalyzed by a B12‐Dependent Enzyme**

J Li, A Kumar, JC Lewis - Angewandte Chemie, 2023 - Wiley Online Library
Despite the unique reactivity of vitamin B12 and its derivatives, B12‐dependent enzymes
remain underutilized in biocatalysis. In this study, we repurposed the B12‐dependent …