The larger acenes: versatile organic semiconductors

JE Anthony - Angewandte Chemie International Edition, 2008 - Wiley Online Library
Acenes have long been the subject of intense study because of the unique electronic
properties associated with their π‐bond topology. Recent reports of impressive …

The MOF-driven synthesis of supported palladium clusters with catalytic activity for carbene-mediated chemistry

FR Fortea-Pérez, M Mon, J Ferrando-Soria… - Nature Materials, 2017 - nature.com
The development of catalysts able to assist industrially important chemical processes is a
topic of high importance. In view of the catalytic capabilities of small metal clusters, research …

Hoehere acene: Vielseitige organische halbleiter

JE Anthony - Angewandte Chemie, 2008 - Wiley Online Library
Acene werden wegen ihrer einzigartigen elektronischen Eigenschaften, die auf der
Topologie ihrer π‐Systeme beruhen, seit langem untersucht. Berichte über die …

Pd8 Nanocluster with Nonmetal‐to‐Metal‐ Ring Coordination and Promising Photothermal Conversion Efficiency

Q You, XL Jiang, W Fan, YS Cui, Y Zhao… - Angewandte …, 2024 - Wiley Online Library
Constructing ambient‐stable, single‐atom‐layered metal‐based materials with atomic
precision and understanding their underlying stability mechanisms are challenging. Here …

Well-Defined Pdn Clusters for Cross-Coupling and Hydrogenation Catalysis: New Opportunities for Catalyst Design

N Jeddi, NWJ Scott, IJS Fairlamb - ACS Catalysis, 2022 - ACS Publications
In recent studies it has been demonstrated that the privileged reactivity of higher-order metal
clusters can be exploited in widely applied catalytic processes, particularly cross-coupling …

Self-assembly, structural transformation, and guest-binding properties of supramolecular assemblies with triangular metal–metal bonded units

LJ Wang, X Li, S Bai, YY Wang… - Journal of the American …, 2020 - ACS Publications
The properties of supramolecular structures are highly dependent on their metal-centered
building blocks and organic linkers, thus the search for novel systems will lead to new …

Palladium clusters confined in triazinyl-functionalized COFs with enhanced catalytic activity

M Fan, WD Wang, Y Zhu, X Sun, F Zhang… - Applied Catalysis B …, 2019 - Elsevier
Noble-metal-cluster-based catalysts have attracted immense research attention due to their
high atom utilization ratio and superior catalytic activity. However, it is still challenging to …

A Robust and Efficient Pd3 Cluster Catalyst for the Suzuki Reaction and Its Odd Mechanism

F Fu, J **ang, H Cheng, L Cheng, H Chong… - ACS …, 2017 - ACS Publications
The palladium-catalyzed Suzuki–Miyaura coupling reaction is one of the most versatile and
powerful tools for constructing synthetically useful unsymmetrical aryl–aryl bonds. In …

Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral‐at‐Cluster Photoluminescence

S Horiuchi, S Moon, A Ito, J Tessarolo… - Angewandte …, 2021 - Wiley Online Library
Multinuclear Ag clusters sandwiched by Pt complex units were synthesized and
characterized by single crystal X‐ray diffraction and NMR studies. The sandwich‐shaped …

“Template synthesis” of discrete metal clusters with two-or three-dimensional architectures

Y Sunada, K Yamaguchi, K Suzuki - Coordination Chemistry Reviews, 2022 - Elsevier
Discrete transition-metal clusters with metal–metal or metal–oxygen–metal bonds represent
a new category of functional materials with numerous unusual properties. For instance, the …