Conspectus Catalytic atroposelective syntheses of axially chiral compounds have stimulated
extensive interest in multiple communities, such as synthetic chemistry, biochemistry, and …

Conspectus The growing importance of axially chiral architectures in different scientific
domains has unveiled shortcomings in terms of efficient synthetic access and skeletal …

Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …

Conspectus Atropisomerism is a conformational chirality that occurs when there is hindered
rotation about a σ-bond. While atropisomerism is exemplified by biaryls, it is observed in …

Conspectus Atropisomers, arising from conformational restriction, are inherently chiral due
to the intersecting dissymmetric planes. Since there are numerous applications of …

Enantiomers, where chirality arises from restricted rotation around a single bond, are
atropisomers. Due to the unique nature of the origins of their chirality, synthetic strategies to …

This tutorial review provides a systematic overview of the available methodologies for the
atroposelective transformation of (heterobiaryl) biaryl precursors toward the synthesis of …

Conspectus Indole-based chiral heterocycles constitute a class of important heterocyclic
compounds that are found in numerous pharmaceuticals, functional materials, and chiral …

The first highly atroposelective construction of N− N axially chiral indole scaffolds was
established via a new strategy of de novo ring formation. This strategy makes use of the …

Conspectus Axially chiral compounds have received much attention from chemists because
of their widespread appearance in natural products, biologically active compounds, and …