The chaotropic effect as an assembly motif in chemistry
Following up on scattered reports on interactions of conventional chaotropic ions (for
example, I−, SCN−, ClO4−) with macrocyclic host molecules, biomolecules, and …
example, I−, SCN−, ClO4−) with macrocyclic host molecules, biomolecules, and …
The bright future of unconventional σ/π‐hole interactions
Non‐covalent interactions play a crucial role in (supramolecular) chemistry and much of
biology. Supramolecular forces can indeed determine the structure and function of a host …
biology. Supramolecular forces can indeed determine the structure and function of a host …
Molecular recognition in chemical and biological systems
E Persch, O Dumele, F Diederich - … Chemie International Edition, 2015 - Wiley Online Library
Abstract Structure‐based ligand design in medicinal chemistry and crop protection relies on
the identification and quantification of weak noncovalent interactions and understanding the …
the identification and quantification of weak noncovalent interactions and understanding the …
Supramolecular binding thermodynamics by dispersion‐corrected density functional theory
S Grimme - Chemistry–A European Journal, 2012 - Wiley Online Library
The equilibrium association free enthalpies ΔGa for typical supramolecular complexes in
solution are calculated by ab initio quantum chemical methods. Ten neutral and three …
solution are calculated by ab initio quantum chemical methods. Ten neutral and three …
The hydrophobic effect revisited—studies with supramolecular complexes imply high‐energy water as a noncovalent driving force
Traditional descriptions of the hydrophobic effect on the basis of entropic arguments or the
calculation of solvent‐occupied surfaces must be questioned in view of new results obtained …
calculation of solvent‐occupied surfaces must be questioned in view of new results obtained …
Multivalency as a chemical organization and action principle
Multivalent interactions can be applied universally for a targeted strengthening of an
interaction between different interfaces or molecules. The binding partners form cooperative …
interaction between different interfaces or molecules. The binding partners form cooperative …
Putting anion–π interactions into perspective
Supramolecular chemistry is a field of scientific exploration that probes the relationship
between molecular structure and function. It is the chemistry of the noncovalent bond, which …
between molecular structure and function. It is the chemistry of the noncovalent bond, which …
Quasi‐solid‐state rechargeable lithium‐ion batteries with a calix [4] quinone cathode and gel polymer electrolyte
Rechargeable lithium-ion batteries (LIBs), which are currently based on the exchange of
Li/Li+ between a graphite (LixC6) anode and an inorganic lithium-transition-metaloxide …
Li/Li+ between a graphite (LixC6) anode and an inorganic lithium-transition-metaloxide …
Deep inside cucurbiturils: physical properties and volumes of their inner cavity determine the hydrophobic driving force for host–guest complexation
WM Nau, M Florea, KI Assaf - Israel Journal of Chemistry, 2011 - Wiley Online Library
Abstract Cucurbit [n] urils (CBn) bind guest molecules through a combination of electrostatic
interactions with the carbonyl rims and hydrophobic interactions with the inner cavity …
interactions with the carbonyl rims and hydrophobic interactions with the inner cavity …
Cucurbit[n]urils for Supramolecular Catalysis
B Tang, J Zhao, JF Xu, X Zhang - Chemistry–A European …, 2020 - Wiley Online Library
The control over chemical reactivity and selectivity are always pursued. Using non‐covalent
interactions to achieve efficient and selective catalysis is an essential goal of …
interactions to achieve efficient and selective catalysis is an essential goal of …