Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Evaporation-induced self-assembly of metal oxide inverse opals: From synthesis to applications

JES Hoeven, AV Shneidman, NJ Nicolas… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Inverse opals (IOs) are highly interconnected three-dimensional macroporous
structures with applications in a variety of disciplines from optics to catalysis. For instance …

Decoding reactive structures in dilute alloy catalysts

N Marcella, JS Lim, AM Płonka, G Yan, CJ Owen… - Nature …, 2022 - nature.com
Rational catalyst design is crucial toward achieving more energy-efficient and sustainable
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …

Design of Dilute Palladium–Indium Alloy Catalysts for the Selective Hydrogenation of CO2 to Methanol

AM Alamer, M Ouyang, FH Alshafei, MA Nadeem… - ACS …, 2023 - ACS Publications
Adding small amounts of a more reactive dopant metal to a more selective host metal is a
well-known strategy for promoting the catalytic reactivity of the latter without sacrificing its …

[HTML][HTML] High-performance water gas shift induced by asymmetric oxygen vacancies: Gold clusters supported by ceria-praseodymia mixed oxides

J Shi, H Li, A Genest, W Zhao, P Qi, T Wang… - Applied Catalysis B …, 2022 - Elsevier
Modifying and controlling sites at the metal/oxide interface is an effective way of tuning
catalytic activity, beneficial for bifunctional catalysis by reducible oxide supported metal …

Strategies to improve hydrogen activation on gold catalysts

N Dimitratos, G Vilé, S Albonetti, F Cavani… - Nature Reviews …, 2024 - nature.com
Catalytic reactions involving molecular hydrogen are at the heart of many transformations in
the chemical industry. Classically, hydrogenations are carried out on Pd, Pt, Ru or Ni …

Dynamical study of adsorbate-induced restructuring kinetics in bimetallic catalysts using the PdAu (111) model system

C Zhou, HT Ngan, JS Lim, Z Darbari… - Journal of the …, 2022 - ACS Publications
Dynamic restructuring of bimetallic catalysts plays a crucial role in their catalytic activity and
selectivity. In particular, catalyst pretreatment with species such as carbon monoxide and …

Restructuring dynamics of surface species in bimetallic nanoparticles probed by modulation excitation spectroscopy

PK Routh, E Redekop, S Prodinger… - Nature …, 2024 - nature.com
Restructuring of metal components on bimetallic nanoparticle surfaces in response to the
changes in reactive environment is a ubiquitous phenomenon whose potential for the …

Identifying the optimal Pd ensemble size in dilute PdAu alloy nanomaterials for benzaldehyde hydrogenation

SK Kaiser, JES Van Der Hoeven, G Yan, KRG Lim… - ACS …, 2023 - ACS Publications
Unraveling metal nuclearity effects is central for active site identification and the
development of high-performance heterogeneous catalysts. Herein, a platform of …

Zeolite fixed cobalt–nickel nanoparticles for coking and sintering resistance in dry reforming of methane

Q Zhu, Y Liu, X Qin, L Liu, Z Ren, X Tao, C Wang… - Chemical Engineering …, 2023 - Elsevier
Dry reforming of methane (DRM) displays a crucial role in CO 2 fixation, but the current
catalysts suffer from deactivation from thermodynamically oriented coking and metal …