Metallo‐Supramolecular Self‐Assembly with Reduced‐Symmetry Ligands

JEM Lewis, JD Crowley - ChemPlusChem, 2020 - Wiley Online Library
Metallo‐supramolecular self‐assembly tends to be performed with single metal ions and
single, highly symmetrical, ligands. This simplifies the self‐assembly process as without …

Photoswitchable Imines Drive Dynamic Covalent Systems to Nonequilibrium Steady States

J Wu, JL Greenfield - Journal of the American Chemical Society, 2024 - ACS Publications
Coupling a photochemical reaction to a thermal exchange process can drive the latter to a
nonequilibrium steady state (NESS) under photoirradiation. Typically, systems use separate …

Self-sorting assembly of artificial building blocks

Q Liu, B **, Q Li, H Yang, Y Luo, X Li - Soft Matter, 2022 - pubs.rsc.org
Self-assembly to build high-level structures, which is ubiquitous in living systems, has
captured the imagination of scientists, striving to emulate the intricacy, homogeneity and …

Narcissistic, integrative, and kinetic self-sorting within a system of coordination cages

FJ Rizzuto, JR Nitschke - Journal of the American Chemical …, 2020 - ACS Publications
Many useful principles of self-assembly have been elucidated through studies of systems
where multiple components combine to create a single structure. More complex systems …

Transformation Network Culminating in a Heteroleptic Cd6L6L′2 Twisted Trigonal Prism

D Zhang, TK Ronson, L Xu… - Journal of the American …, 2020 - ACS Publications
Transformations between three-dimensional metallosupramolecular assemblies can enable
switching between the different functions of these structures. Here we report a network of …

Dynamic covalent self-sorting and kinetic switching processes in two cyclic orders: Macrocycles and macrobicyclic cages

Z Yang, JM Lehn - Journal of the American Chemical Society, 2020 - ACS Publications
Dynamic covalent component self-sorting processes have been investigated for constituents
of different cyclic orders, macrocycles and macrobicyclic cages based on multiple reversible …

Transient self-assembly of metal–organic complexes

JF Ayme, B Bruchmann, L Karmazin, N Kyritsakas - Chemical Science, 2023 - pubs.rsc.org
Implementing transient processes in networks of dynamic molecules holds great promise for
develo** new functional behaviours. Here we report that trichloroacetic acid can be used …

Simultaneous generation of a [2× 2] grid-like complex and a linear double helicate: a three-level self-sorting process

JF Ayme, JM Lehn, C Bailly… - Journal of the American …, 2020 - ACS Publications
Two constitutional dynamic libraries (CDLs)—each containing two amines, two dialdehydes,
and two metal salts—have been found to self-sort, generating two pairs of imine-based …

Pattern generation and information transfer through a liquid/liquid interface in 3D constitutional dynamic networks of imine ligands in response to metal cation effectors

A Osypenko, S Dhers, JM Lehn - Journal of the American …, 2019 - ACS Publications
The immense discriminative capacity of the human olfactory chemosensory systems relies
on the generation of a combinatorial signal in response to the interaction of a particular …

Reaction Kinetics using a Chemputable Framework for Data Collection and Analysis

BM Matysiak, D Thomas, L Cronin - Angewandte Chemie, 2024 - Wiley Online Library
Automated chemistry platforms have been widely explored, but many focus on fixed tasks for
chemical synthesis or analysis. However, a typical synthetic chemistry workflow utilizes both …