Metallo‐Supramolecular Self‐Assembly with Reduced‐Symmetry Ligands
Metallo‐supramolecular self‐assembly tends to be performed with single metal ions and
single, highly symmetrical, ligands. This simplifies the self‐assembly process as without …
single, highly symmetrical, ligands. This simplifies the self‐assembly process as without …
Photoswitchable Imines Drive Dynamic Covalent Systems to Nonequilibrium Steady States
Coupling a photochemical reaction to a thermal exchange process can drive the latter to a
nonequilibrium steady state (NESS) under photoirradiation. Typically, systems use separate …
nonequilibrium steady state (NESS) under photoirradiation. Typically, systems use separate …
Self-sorting assembly of artificial building blocks
Q Liu, B **, Q Li, H Yang, Y Luo, X Li - Soft Matter, 2022 - pubs.rsc.org
Self-assembly to build high-level structures, which is ubiquitous in living systems, has
captured the imagination of scientists, striving to emulate the intricacy, homogeneity and …
captured the imagination of scientists, striving to emulate the intricacy, homogeneity and …
Narcissistic, integrative, and kinetic self-sorting within a system of coordination cages
Many useful principles of self-assembly have been elucidated through studies of systems
where multiple components combine to create a single structure. More complex systems …
where multiple components combine to create a single structure. More complex systems …
Transformation Network Culminating in a Heteroleptic Cd6L6L′2 Twisted Trigonal Prism
Transformations between three-dimensional metallosupramolecular assemblies can enable
switching between the different functions of these structures. Here we report a network of …
switching between the different functions of these structures. Here we report a network of …
Dynamic covalent self-sorting and kinetic switching processes in two cyclic orders: Macrocycles and macrobicyclic cages
Z Yang, JM Lehn - Journal of the American Chemical Society, 2020 - ACS Publications
Dynamic covalent component self-sorting processes have been investigated for constituents
of different cyclic orders, macrocycles and macrobicyclic cages based on multiple reversible …
of different cyclic orders, macrocycles and macrobicyclic cages based on multiple reversible …
Transient self-assembly of metal–organic complexes
JF Ayme, B Bruchmann, L Karmazin, N Kyritsakas - Chemical Science, 2023 - pubs.rsc.org
Implementing transient processes in networks of dynamic molecules holds great promise for
develo** new functional behaviours. Here we report that trichloroacetic acid can be used …
develo** new functional behaviours. Here we report that trichloroacetic acid can be used …
Simultaneous generation of a [2× 2] grid-like complex and a linear double helicate: a three-level self-sorting process
Two constitutional dynamic libraries (CDLs)—each containing two amines, two dialdehydes,
and two metal salts—have been found to self-sort, generating two pairs of imine-based …
and two metal salts—have been found to self-sort, generating two pairs of imine-based …
Pattern generation and information transfer through a liquid/liquid interface in 3D constitutional dynamic networks of imine ligands in response to metal cation effectors
The immense discriminative capacity of the human olfactory chemosensory systems relies
on the generation of a combinatorial signal in response to the interaction of a particular …
on the generation of a combinatorial signal in response to the interaction of a particular …
Reaction Kinetics using a Chemputable Framework for Data Collection and Analysis
Automated chemistry platforms have been widely explored, but many focus on fixed tasks for
chemical synthesis or analysis. However, a typical synthetic chemistry workflow utilizes both …
chemical synthesis or analysis. However, a typical synthetic chemistry workflow utilizes both …