From Liquid to Solid‐State Batteries: Li‐Rich Mn‐Based Layered Oxides as Emerging Cathodes with High Energy Density

WJ Kong, CZ Zhao, S Sun, L Shen… - Advanced …, 2024 - Wiley Online Library
Li‐rich Mn‐based (LRMO) cathode materials have attracted widespread attention due to
their high specific capacity, energy density, and cost‐effectiveness. However, challenges …

Voltage decay of Li‐rich layered oxides: mechanism, modification strategies, and perspectives

L Zeng, H Liang, B Qiu, Z Shi, S Cheng… - Advanced Functional …, 2023 - Wiley Online Library
Li‐rich layered oxides (LLOs) have been considered as the most promising cathode
materials for achieving high energy density Li‐ion batteries. However, they suffer from …

Regulation of coordination chemistry for ultrastable layered oxide cathode materials of sodium‐ion batteries

S Gao, Z Zhu, H Fang, K Feng, J Zhong… - Advanced …, 2024 - Wiley Online Library
Layered transition‐metal (TM) oxide cathodes have attracted growing attention in sodium‐
ion batteries (SIBs). However, their practical implementation is plagued by Jahn–Teller …

Boosting the reversibility and kinetics of anionic redox chemistry in sodium-ion oxide cathodes via reductive coupling mechanism

Y Wang, X Zhao, J **, Q Shen, Y Hu… - Journal of the …, 2023 - ACS Publications
Activating anionic redox chemistry in layered oxide cathodes is a paradigmatic approach to
devise high-energy sodium-ion batteries. Unfortunately, excessive oxygen redox usually …

Cathode electrolyte interface engineering by gradient fluorination for high‐performance lithium rich cathode

L Di, C Yufang, S Weiwei, X Wei… - Advanced Energy …, 2023 - Wiley Online Library
Despite their ultrahigh specific capacity, lithium‐rich layered oxide cathodes are still plagued
by challenges such as poor cycle stability and notorious voltage decay, which are primarily …

Formulating local environment of oxygen mitigates voltage hysteresis in Li‐rich materials

M Zhang, L Qiu, W Hua, Y Song, Y Deng… - Advanced …, 2024 - Wiley Online Library
Li‐rich cathode materials have emerged as one of the most prospective options for Li‐ion
batteries owing to their remarkable energy density (> 900 Wh kg− 1). However, voltage …

Li/Ni Intermixing: The Real Origin of Lattice Oxygen Stability in Co‐Free Ni‐Rich Cathode Materials

Y Song, Y Cui, L Geng, B Li, L Ge… - Advanced Energy …, 2024 - Wiley Online Library
Abstract The Co‐free Ni‐rich layered cathode materials with excellent structural stability and
low‐cost in Ni‐rich family are emerging as the promising candidates for the next generation …

Challenges in high-throughput inorganic materials prediction and autonomous synthesis

J Leeman, Y Liu, J Stiles, SB Lee, P Bhatt, LM Schoop… - PRX Energy, 2024 - APS
Materials discovery lays the foundation for many technological advancements. The
prediction and discovery of new materials are not simple tasks. Here, we outline some basic …

Manipulating disorder within cathodes of alkali-ion batteries

S Kang, S Lee, H Lee, YM Kang - Nature Reviews Chemistry, 2024 - nature.com
The fact that ordered materials are rarely perfectly crystalline is widely acknowledged
among materials scientists, but its impact is often overlooked or underestimated when …

Unraveling the functioning mechanism of fluorine-do** in Mn-based layered oxide cathodes toward enhanced sodium-ion storage performance

X Song, R Liu, J **, X Zhao, Y Wang, Q Shen… - Energy Storage …, 2024 - Elsevier
Manganese-based layered oxides with anionic redox activity are considered as one of the
most promising cathode candidates for sodium-ion batteries (SIBs) owing to their abundant …