A critical review on emerging photoactive porous materials for sulfide oxidation and sulfur mustards decontamination

P Kalita, R Paul, A Boruah, DQ Dao, A Bhaumik… - Green …, 2023 - pubs.rsc.org
Chemical warfare agents (CWAs) have been classified as fatal weapons of mass destruction
because of their toxicity and deadly consequences. Among other CWAs, sulfur mustards …

Will the next generation of chemical plants be in miniaturized flow reactors?

JCM Monbaliu, J Legros - Lab on a Chip, 2023 - pubs.rsc.org
For decades, a production paradigm based on centralized, stepwise, large scale processes
has dominated the chemical industry horizon. While effective to meet an ever increasing …

Liquid–liquid extraction for in situ carboxylic acid recovery via continuous membrane-based emulsion separations

Y Chen, PO Saboe, JS Kruger, ECD Tan… - Green …, 2024 - pubs.rsc.org
The separation and purification of bio-based chemicals from conversion processes often
contribute substantially to bioprocessing costs, and for many biochemicals produced …

Putting forward a Ni-metallosalphen-based porous organic polymer for detoxification of sulfur mustard gas simulant

P Kalita, R Paul, CW Pao, R Chatterjee… - Chemical …, 2023 - pubs.rsc.org
We have introduced a Friedel–Crafts alkylation strategy of a Ni-salphen complex as derived
from 2-hydroxy-5-methoxybenzaldehyde, an isomer of biomass derived vanillin, to construct …

A miniaturized ozonolysis flow platform for expeditious sulfur mustard warfare simulant neutralization

M Boddaert, P Bianchi, DV Silva-Brenes, A Musina… - Green …, 2024 - pubs.rsc.org
This communication introduces a highly efficient, safe and sustainable flow protocol for the
oxidative neutralization of sulfur-based chemical warfare agent simulants using ozone. The …

Harnessing a Continuous‐Flow Persulfuric Acid Generator for Direct Oxidative Aldehyde Esterifications

BS Nagy, G Fu, CA Hone, CO Kappe… - …, 2023 - Wiley Online Library
Persulfuric acid is a well‐known oxidant in various industrial‐scale purification procedures.
However, due to its tendency toward explosive decomposition, its usefulness in organic …

One-pot thiol-free synthetic approach to sulfides, and sulfoxides selectively

S Kotha, NK Gupta, S Ansari - RSC advances, 2022 - pubs.rsc.org
A facile and efficient thiol-free one-pot method for direct synthesis of sulfides and sulfoxides
under green conditions without using any metal catalyst is reported. For this purpose, we …

Soft detoxification of chemical warfare agent simulants and pesticides under pressure

S Mansour, VB Silva, ES Orth, J Legros - Organic & Biomolecular …, 2022 - pubs.rsc.org
The neutralisation of structurally varied chemical warfare agent simulants (blister and nerve
agents) and pesticides (Paraoxon) with the assistance of high pressure is reported …

[HTML][HTML] Expedient, metal-, extraction-and generally purification-free, temperature-and solvent-directed oxidation of diaryl sulfides using t-BuOCl

A Zupanc, Č Podlipnik, RC Korošec, M Jereb - Journal of Cleaner …, 2025 - Elsevier
An environmentally friendly, operationally simple and convenient, scalable, temperature-and
solvent-directed oxidation of hydrophobic sulfides that yields sulfoxides and sulfones is …

Flow detoxification of a sulfur mustard simulant with organometallic compounds enabled by an optimization algorithm

VB da Silva, S Mansour, A Delaune… - Reaction Chemistry & …, 2023 - pubs.rsc.org
The flow detoxification of the yperite simulant CEES (chloroethyl ethyl sulfide) with PhMgBr
or PhLi proceeds in a faster fashion than in a classical batch reactor, to afford the …