Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics

A Mandal, MAD Taylor, BM Weight… - Chemical …, 2023 - ACS Publications
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

Quantum dynamical effects of vibrational strong coupling in chemical reactivity

LP Lindoy, A Mandal, DR Reichman - Nature Communications, 2023 - nature.com
Recent experiments suggest that ground state chemical reactivity can be modified when
placing molecular systems inside infrared cavities where molecular vibrations are strongly …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

RETRACTED: Solvent polarity under vibrational strong coupling

M Piejko, B Patrahau, K Joseph, C Muller… - Journal of the …, 2023 - ACS Publications
Vibrational strong coupling (VSC) occurs when molecular vibrations hybridize with the
modes of an optical cavity, an interaction mediated by vacuum fluctuations. VSC has been …

Cavity-enabled enhancement of ultrafast intramolecular vibrational redistribution over pseudorotation

TT Chen, M Du, Z Yang, J Yuen-Zhou, W **ong - Science, 2022 - science.org
Vibrational strong coupling (VSC) between molecular vibrations and microcavity photons
yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic …

Direct observation of polaritonic chemistry by nuclear magnetic resonance spectroscopy

B Patrahau, M Piejko, RJ Mayer… - Angewandte Chemie …, 2024 - Wiley Online Library
Polaritonic chemistry is emerging as a powerful approach to modifying the properties and
reactivity of molecules and materials. However, probing how the electronics and dynamics of …