Here, we report a photoredox and nickel-catalyzed cross-electrophile coupling strategy for
the asymmetric three-component 1, 2-alkylarylation of vinyl boronates with (hetero) aryl …

Chiral alpha-amino ketones have found extensive applications as functional molecules. A
nickel-catalyzed, enantioselective, and fully intermolecular three-component 1, 2 …

Introducing saturated carbon-carbon bonds into organic molecules significantly increases
the three-dimensional configuration, thus altering the physical and chemical properties as …

We report a Ni-catalyzed vicinal alkylarylation of unactivated alkenes in γ, δ-and δ, ε-
alkenylamines with aryl halides and alkylzinc reagents. The reaction is enabled by amine …

The development of a catalytic method for stereogenic carbon center formation holds
immense significance in organic synthesis. Transition-metal-catalyzed cross-coupling …

The enantioselective three-component dicarbonfunctionalization of electronically
unactivated alkenes continues to pose a significant challenge. In this work, a copper …

Catalytic methods allow for regioselective and site-divergent transformations for rapid
construction of different complex architectures from identical and readily-available starting …

Herein we reported a manganese promoted reductive cross‐coupling approach to construct
P‒S bond. This is a practical method for the synthesis of mono‐thiophosphanes, bis …

Comprehensive Summary Herein, an unprecedented nickel‐catalyzed regioselective
hydroalkynylation of unsymmetrical internal alkynes was realized with steric hindered …

Difunctionalizations of alkenes represent one of the most straightforward protocols to build
molecular complexity due to the simultaneous construction of two vicinal bonds cross π …