A review of the innovations in metal-and carbon-based catalysts explored for heterogeneous peroxymonosulfate (PMS) activation, with focus on radical vs. non-radical …

M Kohantorabi, G Moussavi, S Giannakis - Chemical Engineering Journal, 2021‏ - Elsevier
The heterogeneous, sulfate radical-based AOPs (SR-AOPs) have emerged over the last
decade as a highly potent technology for the removal of various organic contaminants from …

Activation of persulfates by carbonaceous materials: A review

W Huang, S **ao, H Zhong, M Yan, X Yang - Chemical Engineering …, 2021‏ - Elsevier
In recent years, persulfate-based advanced oxidation processes (PS-AOPs) for removal of
organic contaminants from water have gained wide attention. Ever-emerging carbonaceous …

Ultrafast degradation of emerging organic pollutants via activation of peroxymonosulfate over Fe3C/Fe@ NCx: Singlet oxygen evolution and electron-transfer …

C Zhao, L Meng, H Chu, JF Wang, T Wang, Y Ma… - Applied Catalysis B …, 2023‏ - Elsevier
Abstract Fe 3 C/Fe decorated N-doped magnetic carbon materials (denoted as Fe 3 C/Fe@
NC-x) were successfully fabricated via facile one-pot calcination of MIL-88B (Fe) with a …

Correlation of active sites to generated reactive species and degradation routes of organics in peroxymonosulfate activation by Co-loaded carbon

N Li, R Li, X Duan, B Yan, W Liu, Z Cheng… - Environmental …, 2021‏ - ACS Publications
Peroxymonosulfate (PMS)-based advanced oxidation processes (PMS-AOPs) as an efficient
strategy for organic degradation are highly dependent on catalyst design and structured …

Switching the reaction mechanisms and pollutant degradation routes through active center size-dependent Fenton-like catalysis

X Wang, Z **ong, H Shi, Z Wu, B Huang… - Applied Catalysis B …, 2023‏ - Elsevier
Rationally regulating reaction mechanisms in Fenton-like reactions by tuning the properties
of catalysts is of great significance, but still challenging. Herein, we synthesized various …

Density functional theory calculations for insight into the heterocatalyst reactivity and mechanism in persulfate-based advanced oxidation reactions

P Zhang, Y Yang, X Duan, Y Liu, S Wang - ACS catalysis, 2021‏ - ACS Publications
Advanced oxidation processes (AOPs) based on persulfates such as peroxymonosulfate
and peroxydisulfate via heterogeneous catalysts have been a research hotspot due to their …

Heterogeneous activation of persulfate by metal and non-metal catalyst for the degradation of sulfamethoxazole: A review

DT Oyekunle, EA Gendy, J Ifthikar, Z Chen - Chemical Engineering Journal, 2022‏ - Elsevier
Sulfamethoxazole (SMX) is a high-priority pharmaceutical that is widely used as an antibiotic
and fungicide. It can be partially metabolized by animal and human bodies, hence a large …

Carbonized polyaniline activated peroxymonosulfate (PMS) for phenol degradation: Role of PMS adsorption and singlet oxygen generation

S Liu, Z Zhang, F Huang, Y Liu, L Feng, J Jiang… - Applied Catalysis B …, 2021‏ - Elsevier
N-doped carbonaceous materials are promising efficient catalysts for peroxymonosulfate
(PMS) activation. In this study, the high-efficient N-doped carbon materials were prepared by …

Activation of peroxymonosulfate by biochar-based catalysts and applications in the degradation of organic contaminants: A review

C Zhao, B Shao, M Yan, Z Liu, Q Liang, Q He… - Chemical Engineering …, 2021‏ - Elsevier
Sulfate radical-based advanced oxidation processes (SR-AOPs) have received intensively
attention due to the ability and adaptability. Biochar-based catalysts have been regarded as …

Enhanced Interfacial Electron Transfer by Asymmetric Cu‐Ov‐In Sites on In2O3 for Efficient Peroxymonosulfate Activation

Z Zhao, P Wang, C Song, T Zhang… - Angewandte Chemie …, 2023‏ - Wiley Online Library
Enhancing the peroxymonosulfate (PMS) activation efficiency to generate more radicals is
vital to promote the Fenton‐like reaction activity, however, how to promote the PMS …