Endohedrally doped cage clusters

J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …

Recent advances in structural chemistry of Group 14 Zintl ions

C Liu, ZM Sun - Coordination Chemistry Reviews, 2019 - Elsevier
The solution chemistry of Group 14 Zintl-type clusters is of growing interest as a result of
their potential to be used as molecular building blocks for the construction of nanoscale …

Vanadium-doped small silicon clusters: Photoelectron spectroscopy and density-functional calculations

HG Xu, ZG Zhang, Y Feng, J Yuan, Y Zhao… - Chemical Physics …, 2010 - Elsevier
Vanadium-doped small silicon clusters, VSin-and V2Sin-(n= 3–6), have been studied by
anion photoelectron spectroscopy. The vertical detachment energies (VDEs) and adiabatic …

Multiple valence superatoms

JU Reveles, SN Khanna, PJ Roach… - Proceedings of the …, 2006 - National Acad Sciences
We recently demonstrated that, in gas phase clusters containing aluminum and iodine
atoms, an Al13 cluster behaves like a halogen atom, whereas an Al14 cluster exhibits …

Electronic and geometric stabilities of clusters with transition metal encapsulated by silicon

K Koyasu, J Atobe, M Akutsu, M Mitsui… - The Journal of …, 2007 - ACS Publications
Silicon clusters mixed with a transition metal atom, MSi n, were generated by a double-laser
vaporization method, and the electronic and geometric stabilities for the resulting clusters …

Anion photoelectron spectroscopy of transition metal-and lanthanide metal-silicon clusters: MSin−(n= 6–20)

K Koyasu, J Atobe, S Furuse… - The Journal of chemical …, 2008 - pubs.aip.org
The electronic properties of silicon clusters containing a transition or lanthanide metal atom
from group 3, 4, or 5, M Si n⁠,(⁠ M= Sc⁠, Ti, V, Y, Zr, Nb, Lu, Tb, Ho, Hf, and Ta) were …

Discovery of a silicon-based ferrimagnetic wheel structure in V x Si 12−(x= 1–3) clusters: Photoelectron spectroscopy and density functional theory investigation

X Huang, HG Xu, S Lu, Y Su, RB King, J Zhao… - Nanoscale, 2014 - pubs.rsc.org
Our studies show that VSi12− adopts a V-centered hexagonal prism with a singlet spin state.
The addition of the second V atom leads to a capped hexagonal antiprism for V2Si12− in a …

Anion photoelectron spectroscopy of germanium and tin clusters containing a transition-or lanthanide-metal atom; MGe n−(n= 8–20) and MSn n−(n= 15–17)(M= Sc–V …

J Atobe, K Koyasu, S Furuse… - Physical Chemistry …, 2012 - pubs.rsc.org
The electronic properties of germanium and tin clusters containing a transition-or lanthanide-
metal atom from group 3, 4, or 5, MGen (M= Sc, Ti, V, Y, Zr, Nb, Lu, Hf, and Ta) and MSnn …

Anion photoelectron spectroscopy and density functional theory study of TM 2 Si n−(TM= V, Cr; n= 14–20) clusters

K Wang, GJ Yin, ZZ Jia, L Miao, R Moro… - Physical Chemistry …, 2022 - pubs.rsc.org
We investigated the structural evolution and electronic properties of medium-sized silicon
cluster anions doped with two transition metal atoms, TM2Sin−(TM= V, Cr; n= 14–20), by …

Structures and electronic properties of VSi n−(n= 14–20) clusters: a combined experimental and density functional theory study

K Wang, ZZ Jia, Z Fan, HY Zhao, GJ Yin… - Physical Chemistry …, 2022 - pubs.rsc.org
We present a systematic study of the structures and electronic properties of vanadium-doped
silicon cluster anions, VSin−(n= 14–20), by combining photoelectron spectroscopy (PES) …