Advances of atomically dispersed catalysts from single-atom to clusters in energy storage and conversion applications
Owing to the special structural characteristics and maximized efficiency, atomically
dispersed catalysts (ADCs) with different atom sizes ranged from the single atom to clusters …
dispersed catalysts (ADCs) with different atom sizes ranged from the single atom to clusters …
Beyond ammonia: nitrogen–element bond forming reactions with coordinated dinitrogen
The functionalization of coordinated dinitrogen to form nitrogen–element bonds en route to
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …
Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions
Y Tanabe, Y Nishibayashi - Chemical Society Reviews, 2021 - pubs.rsc.org
N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …
whereas biological nitrogen fixation is achieved under ambient conditions, which has …
Nitrogen reduction by the Fe sites of synthetic [Mo3S4Fe] cubes
Y Ohki, K Munakata, Y Matsuoka, R Hara, M Kachi… - Nature, 2022 - nature.com
Nitrogen (N2) fixation by nature, which is a crucial process for the supply of bio-available
forms of nitrogen, is performed by nitrogenase. This enzyme uses a unique transition-metal …
forms of nitrogen, is performed by nitrogenase. This enzyme uses a unique transition-metal …
Metal–Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry
Transition metal–sulfur (M–S) compounds are an indispensable means for biological
systems to convert N2 into NH3 (biological N2 fixation), and these may have emerged by …
systems to convert N2 into NH3 (biological N2 fixation), and these may have emerged by …
Active sites identification and engineering of MNC electrocatalysts toward oxygen reduction reaction
X Li, D Wang, S Zha, Y Chu, L Pan, M Wu, C Liu… - International Journal of …, 2024 - Elsevier
Zinc-air batteries (ZABs) and Proton exchange membrane fuel cells (PEMFCs) have
attracted wide attention because of their high energy density. However, the oxygen …
attracted wide attention because of their high energy density. However, the oxygen …
Recent progress with pincer transition metal catalysts for sustainability
L Piccirilli, D Lobo Justo Pinheiro, M Nielsen - Catalysts, 2020 - mdpi.com
Our planet urgently needs sustainable solutions to alleviate the anthropogenic global
warming and climate change. Homogeneous catalysis has the potential to play a …
warming and climate change. Homogeneous catalysis has the potential to play a …
Catalytic nitrogen fixation via direct cleavage of nitrogen–nitrogen triple bond of molecular dinitrogen under ambient reaction conditions
K Arashiba, A Eizawa, H Tanaka… - Bulletin of the …, 2017 - academic.oup.com
We have now found that molybdenum–iodide complexes bearing a PNP-pincer ligand have
a higher catalytic activity than the so far reported molybdenum–dinitrogen complexes for …
a higher catalytic activity than the so far reported molybdenum–dinitrogen complexes for …
Dinitrogen fixation: rationalizing strategies utilizing molecular complexes
Dinitrogen (N2) is the most abundant gas in Earth's atmosphere, but its inertness hinders its
use as a nitrogen source in the biosphere and in industry. Efficient catalysts are hence …
use as a nitrogen source in the biosphere and in industry. Efficient catalysts are hence …
Catalytic reduction of molecular dinitrogen to ammonia and hydrazine using vanadium complexes
Y Sekiguchi, K Arashiba, H Tanaka… - Angewandte Chemie …, 2018 - Wiley Online Library
Newly designed and prepared vanadium complexes bearing anionic pyrrole‐based PNP‐
type pincer and aryloxy ligands were found to work as effective catalysts for the direct …
type pincer and aryloxy ligands were found to work as effective catalysts for the direct …