This review covers fundamental kinetic features of living radical polymerization (LRP).
Theories on polymerization rate Rp and polydispersity index (PDI) and experimental …

The dialkyldiazene or azo-compound initiators, which include azonitriles such as azobis
(isobutyronitrile)(AIBN), are one of the most important classes of initiator being widely used …

Written and peer reviewed by experts from around the globe, Encyclopedia of Polymer
Science and Technology provides up-to-date coverage of traditional topics of continuing …

Controlled radical polymerization (CRP) systems have gained increasing interests for the
past two decades. Numerous publications may be found in the literature reporting …

Kinetic analysis reveals the existence of two competing pathways in the organotellurium-
mediated living radical polymerization (TERP) at elevated temperature. The rate …

The evolution of the bromine end functionality during the bulk atom transfer radical
polymerization (ATRP) of styrene [in the presence of the catalyst CuBr/4, 4′‐di‐(5‐nonyl) …

Incompletely condensed, fluorinated polyhedral oligomeric silsesquioxane with the highly
reactive group of trisodium silanolate was used for the synthesis of an initiator for atom …

The field of living radical polymerization (LRP) is reviewed, with general outcomes and
mechanisms being discussed in a qualitative manner. These polymerizations exhibit living …

Exchange of organic radicals between solution and organo-cobalt complexes is
experimentally observed and the reaction pathway is probed through DFT calculations …

Over the last twenty years, the field of the chemistry of polymerization witnessed enormous
growth through the development of new concepts, catalysts, processes etc. Examples are …