Hydrogen and dihydrogen bonds in the reactions of metal hydrides

NV Belkova, LM Epstein, OA Filippov… - Chemical …, 2016 - ACS Publications
The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …

Coordination and organometallic chemistry of metal− NO complexes

TW Hayton, P Legzdins, WB Sharp - Chemical Reviews, 2002 - ACS Publications
The chemistry of transition-metal-NO complexes, or metal nitrosyls, has taken on added
significance in recent years because of the important role that nitric oxide has been found to …

New types of hydrogen bonding in organometallic chemistry

LM Epstein, ES Shubina - Coordination chemistry reviews, 2002 - Elsevier
The review summarizes the experimental and theoretical advances in the elucidation of the
nature, the structure, the spectral and energetic characteristics of the new types of hydrogen …

CNN pincer ruthenium catalysts for hydrogenation and transfer hydrogenation of ketones: Experimental and computational studies

W Baratta, S Baldino, MJ Calhorda… - … A European Journal, 2014 - Wiley Online Library
Abstract Reaction of [RuCl (CNN)(dppb)](1‐Cl)(HCNN= 2‐aminomethyl‐6‐(4‐methylphenyl)
pyridine; dppb= Ph2P (CH2) 4PPh2) with NaOCH2CF3 leads to the amine‐alkoxide [Ru …

Analysis of hydrogen bonds in crystals

SJ Grabowski - Crystals, 2016 - mdpi.com
The determination of crystal structures provides important information on the geometry of
species constituting crystals and on the symmetry relations between them. Additionally, the …

Influence of Media and Homoconjugate Pairing on Transition Metal Hydride Protonation. An IR and DFT Study on Proton Transfer to CpRuH(CO)(PCy3)

NV Belkova, M Besora, LM Epstein… - Journal of the …, 2003 - ACS Publications
The interaction of the ruthenium hydride complex CpRuH (CO)(PCy3)(1) with proton donors
HOR of different strength was studied in hexane and compared with data in …

[BOOK][B] Spectroscopic properties of inorganic and organometallic compounds: Volume 40

J Yarwood, R Douthwaite, S Duckett - 2009 - books.google.com
Spectroscopic properties of inorganic and organometallic compounds: Volume 40 Page 1
Specialist Periodical Reports Edited by J Yarwood, R Douthwaite and SB Duckett Spectroscopic …

Azole assisted C–H bond activation promoted by an osmium-polyhydride: discerning between N and NH

B Eguillor, MA Esteruelas, I Fernández… - …, 2015 - ACS Publications
The capacity of the hexahydride complex OsH6 (PiPr3) 2 (1) to discern between the nitrogen
atom and the NH unit in the azole assisted aryl C–H bond activation has been investigated …

Structural and spectroscopic properties of rhenium nitrosyl complexes

B Machura - Coordination chemistry reviews, 2005 - Elsevier
Structural and spectroscopic properties of rhenium nitrosyl complexes - ScienceDirect Skip to
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Dihydrogen bonding, proton transfer and beyond: What we can learn from kinetics and thermodynamics

NV Belkova, LM Epstein… - European Journal of …, 2010 - Wiley Online Library
Hydrogen bonding to transition metal hydride complexes and its role in the proton transfer
process has been a subject of the authors' research interest in recent years. The present …