Ascorbate oxidation by iron, copper and reactive oxygen species: Review, model development, and derivation of key rate constants

J Shen, PT Griffiths, SJ Campbell, B Utinger… - Scientific reports, 2021 - nature.com
Ascorbic acid is among the most abundant antioxidants in the lung, where it likely plays a
key role in the mechanism by which particulate air pollution initiates a biological response …

Catalytic chemistry of iron-free Fenton nanocatalysts for versatile radical nanotherapeutics

Q Chen, D Yang, L Yu, X **g, Y Chen - Materials Horizons, 2020 - pubs.rsc.org
The conversion of nontoxic agents into therapeutic species in situ, just within the disease
microenvironment, is the ideal strategy because it can substantially enhance the therapeutic …

Fenton-like copper redox chemistry revisited: Hydrogen peroxide and superoxide mediation of copper-catalyzed oxidant production

AN Pham, G **ng, CJ Miller, TD Waite - Journal of catalysis, 2013 - Elsevier
Copper toxicity has been attributed to its potential as a catalyst for oxidative damage to
tissues through redox cycling between Cu (I) and Cu (II), particularly in the presence of …

Decomplexation of Cu (II)-EDTA by UV/persulfate and UV/H2O2: efficiency and mechanism

Z Xu, C Shan, B **e, Y Liu, B Pan - Applied Catalysis B: Environmental, 2017 - Elsevier
Heavy metal-organic complexes are widely present in natural water and industrial effluents.
Currently, the widely employed strategy for removal of metal-organic complexes is to …

Tumor Microenvironment-Responsive Cu2(OH)PO4 Nanocrystals for Selective and Controllable Radiosentization via the X-ray-Triggered Fenton-like Reaction

C Zhang, L Yan, X Wang, X Dong, R Zhou, Z Gu… - Nano Letters, 2019 - ACS Publications
Traditional radiotherapy can induce injury to the normal tissue around the tumor, so the
development of novel radiosensitizer with high selectivity and controllability that can lead to …

Different valence states of copper ion delivery against triple-negative breast cancer

T He, Q Tang, Q Ren, Y Liu, G He, Y Pan, Z Wang… - ACS …, 2024 - ACS Publications
Different valence states of copper (Cu) ions are involved in complicated redox reactions in
vivo, which are closely related to tumor proliferation and death pathways, such as …

Fenton-like degradation of sulfamethoxazole in Cu0/Zn0-air system over a broad pH range: performance, kinetics and mechanism

Y Liu, Z Yang, J Wang - Chemical Engineering Journal, 2021 - Elsevier
In this study, a bimetallic Cu 0/Zn 0 particles were prepared, characterized and used as
Fenton-like catalyst for the degradation of sulfamethoxazole (SMX). The results showed that …

Anticancer copper pyridine benzimidazole complexes: ROS generation, biomolecule interactions, and cytotoxicity

KE Prosser, SW Chang, F Saraci, PH Le… - Journal of inorganic …, 2017 - Elsevier
Abstract The Cu (II) complex CuCl 2 (pbzH), pbzH= 2-(2-pyridyl) benzimidazole, and
derivatives modified at the non-coordinated nitrogen of the benzimidazole fragment, have …

Contribution of pristine and reduced microbial extracellular polymeric substances of different sources to Cu (II) reduction

H Xu, E He, WJGM Peijnenburg, L Song, L Zhao… - Journal of hazardous …, 2021 - Elsevier
Microbial extracellular polymeric substances (EPS) significantly influence metal behavior in
the environment, but the electron transfer reaction between EPS and copper that determine …

Copper-catalyzed hydroquinone oxidation and associated redox cycling of copper under conditions typical of natural saline waters

X Yuan, AN Pham, CJ Miller… - Environmental science & …, 2013 - ACS Publications
A detailed kinetic model has been developed to describe the oxidation of Cu (I) by O2 and
the reduction of Cu (II) by 1, 4-hydroquinone (H2Q) in the presence of O2 in 0.7 M NaCl …