Structure: function relationships in molecular spin-crossover complexes

MA Halcrow - Chemical Society Reviews, 2011 - pubs.rsc.org
Spin-crossover compounds are becoming increasingly popular for device and sensor
applications, and in soft materials, that make use of their switchable colour, paramagnetism …

Iron (II) complexes of 2, 6-di (pyrazol-1-yl) pyridines—A versatile system for spin-crossover research

MA Halcrow - Coordination Chemistry Reviews, 2009 - Elsevier
Synthetic procedures are available for the derivatisation of almost every position of the 2, 6-
di (pyrazol-1-yl) pyridine (1-bpp) skeleton. This has led to the preparation of a large number …

Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state

C Lochenie, K Schötz, F Panzer, H Kurz… - Journal of the …, 2018 - ACS Publications
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …

Transition metal complexes with tetradentate Schiff bases (N2O2) obtained from salicylaldehyde: A review of their possible anticancer properties

LA Alfonso-Herrera, D Hernández-Romero… - Coordination Chemistry …, 2024 - Elsevier
Despite multiple advances in prevention and treatment, cancer remains a deadly disease
globally. From 1942 to the present day, chemotherapy has been recognized as one of the …

Spin crossover–quo vadis?

P Gütlich - European Journal of Inorganic Chemistry, 2013 - Wiley Online Library
This retrospective essay is an attempt to span the bridge over eight decades of research on
spin crossover (SCO), one of the most fascinating dynamic electron structure phenomena of …

A highly stretchable polymer that can be thermally healed at mild temperature

XY Jia, JF Mei, JC Lai, CH Li… - Macromolecular Rapid …, 2016 - Wiley Online Library
Combining stretchability and self‐healing properties in a man‐made material is a
challenging task. For an efficient self‐healing material, weaker dynamic or reversible bonds …

When the metal makes the difference: Template syntheses of tridentate and tetradentate salen-type schiff base ligands and related complexes

R Mazzoni, F Roncaglia, L Rigamonti - Crystals, 2021 - mdpi.com
The reaction of organic molecules mediated by a metal center (template synthesis) can
result in a final connectivity that may differ from the one obtained in the absence of the metal …

Halogen Substitution Effects on N2O Schiff Base Ligands in Unprecedented Abrupt FeII Spin Crossover Complexes

W Phonsri, DS Macedo, KR Vignesh… - … A European Journal, 2017 - Wiley Online Library
A family of halogen‐substituted Schiff base iron (II) complexes,[FeII (qsal‐X) 2],(qsal‐X= 5‐X‐
N‐(8‐quinolyl) salicylaldimines)) in which X= F (1), Cl (2), Br (3) or I (4) has been …

Iron (II) spin crossover complexes based on a redox active equatorial Schiff-base-like ligand

S Schönfeld, K Dankhoff, D Baabe… - Inorganic …, 2020 - ACS Publications
In this work, two iron (II) coordination compounds with a N2O2 coordinating Schiff base-like
ligand bearing a redox active tetrathiafulvalene (TTF) unit and pyridine or trans-1, 2-bis (4 …

Influence of hydrogen bonding on the hysteresis width in iron (II) spin‐crossover complexes

B Weber, W Bauer, T Pfaffeneder, MM Dîrtu, AD Naik… - 2011 - Wiley Online Library
A detailed investigation on the properties of the high‐temperature and low‐temperature
modifications of the iron (II) spin‐crossover complex [FeL1 (HIm) 2](1) and its isotopic …