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Towards chemistry at absolute zero
The prospect of cooling matter down to temperatures that are close to absolute zero raises
intriguing questions about how chemical reactivity changes under these extreme conditions …
intriguing questions about how chemical reactivity changes under these extreme conditions …
Cold ion–molecule reactions in the extreme environment of a Coulomb crystal
OA Krohn, HJ Lewandowski - The Journal of Physical Chemistry …, 2024 - ACS Publications
Coulomb crystals provide a unique environment in which to study ion-neutral gas-phase
reactions. In these cold, trapped ensembles, we are able to study the kinetics and dynamics …
reactions. In these cold, trapped ensembles, we are able to study the kinetics and dynamics …
Cold and controlled chemical reaction dynamics
J Toscano, HJ Lewandowski… - Physical Chemistry …, 2020 - pubs.rsc.org
The prospect of studying state-to-state chemical reaction dynamics, with full control over all
of the reaction parameters, is becoming a reality for a small number of systems. Thanks to …
of the reaction parameters, is becoming a reality for a small number of systems. Thanks to …
Reactions of acetonitrile with trapped, translationally cold acetylene cations
The reaction of the acetylene cation (C2H2+) with acetonitrile (CH3CN) is measured in a
linear Paul ion trap coupled to a time-of-flight mass spectrometer. C2H2+ and CH3CN are …
linear Paul ion trap coupled to a time-of-flight mass spectrometer. C2H2+ and CH3CN are …
Inverse kinetic isotope effects in the charge transfer reactions of ammonia with rare gas ions
In the absence of experimental data, models of complex chemical environments rely on
predicted reaction properties. Astrochemistry models, for example, typically adopt variants of …
predicted reaction properties. Astrochemistry models, for example, typically adopt variants of …
To form or not to form a reaction complex: exploring ion–molecule reactions between C 3 H 4 isomers and Xe+ and O 2+
Ion–molecule reactions are an essential contributor to the chemistry of a diverse range of
environments. While a great deal of work has been done to understand the fundamental …
environments. While a great deal of work has been done to understand the fundamental …
Conformational and state-specific effects in reactions of 2, 3-dibromobutadiene with Coulomb-crystallized calcium ions
Recent advances in experimental methodology enabled studies of the quantum-state-and
conformational dependence of chemical reactions under precisely controlled conditions in …
conformational dependence of chemical reactions under precisely controlled conditions in …
Isomer-selected ion–molecule reactions of acetylene cations with propyne and allene
One of the fundamental goals of chemistry is to determine how molecular structure
influences interactions and leads to different reaction products. Studies of isomer-selected …
influences interactions and leads to different reaction products. Studies of isomer-selected …
[HTML][HTML] Isotope-specific reactions of acetonitrile (CH3CN) with trapped, translationally cold CCl+
The gas-phase reaction of CCl+ with acetonitrile (CH 3 CN) is studied using a linear Paul
ion trap coupled to a time-of-flight mass spectrometer. This work builds on a previous study …
ion trap coupled to a time-of-flight mass spectrometer. This work builds on a previous study …
[HTML][HTML] Reactions of translationally cold trapped CCl+ with acetylene (C2H2)
Ion–neutral chemical reactions are important in several areas of chemistry, including in
some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of …
some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of …