Transformations of modified morita‐baylis‐hillman adducts from isatins catalyzed by lewis bases

ZC Chen, Z Chen, W Du, YC Chen - The Chemical Record, 2020‏ - Wiley Online Library
The development of synthetic protocols to access architectures with broad structural and
functional diversity from readily available starting materials is very attractive in both organic …

Recent Advances in Nucleophilic Lewis Base‐Catalyzed Cycloadditions for Synthesis of Spirooxindoles

QF Li, J Ma, J Meng, EQ Li - Advanced Synthesis & Catalysis, 2023‏ - Wiley Online Library
Spirooxindoles are privileged scaffolds in diverse bioactive natural products and
pharmaceuticals, significant achievements for the construction of these molecules have thus …

Convenient Synthetic Protocols for Diverse Functionalized Dihydrobenzofuran-Fused Spiro-indanedione-oxindole Scaffolds

J Sun, X Liu, Q Sun, Y Han, CG Yan - The Journal of Organic …, 2023‏ - ACS Publications
Diverse functionalized dihydrobenzofuran spiro-indanedione-oxindole scaffolds were
conveniently synthesized by base-promoted cyclization reaction of Morita–Baylis–Hillman …

An access to highly functionalized dihydrobenzofuran spirooxindole scaffolds

D Wang, J Sun, Y Han, Q Sun, CG Yan - Organic Letters, 2022‏ - ACS Publications
We have developed an efficient protocol for the construction of polycyclic dihydrobenzofuran
spirooxindole scaffolds via base promoted cascade annulation of Morita–Baylis–Hillman …

Unmasking the reverse reactivity of cyclic N-sulfonyl ketimines: multifaceted applications in organic synthesis

S Guin, D Majee, S Samanta - Chemical Communications, 2021‏ - pubs.rsc.org
The chemistry related to the exploration of cyclic N-sulfonyl ketimines and their derivatives
has attracted significant attention in the last few decades because of their intriguing …

Efficient construction of diverse spiro [indoline-3, 4′-pyrrolo [3, 4-b] pyridines] via [3+ 3] cycloaddition of MBH carbonates of isatins with β-enamino maleimides

LN Pan, J Sun, XY Liu, CG Yan - Organic & Biomolecular Chemistry, 2022‏ - pubs.rsc.org
An efficient method to construct unique spiro [indoline-3, 4′-pyrrolo [3, 4-b] pyridines] was
successfully developed via a DABCO promoted formal [3+ 3] cycloaddition reaction of MBH …

Organocatalytic asymmetric synthesis of multifunctionalized α-carboline-spirooxindole hybrids that suppressed proliferation in colorectal cancer cells

XH He, XJ Fu, G Zhan, N Zhang, X Li, HP Zhu… - Organic Chemistry …, 2022‏ - pubs.rsc.org
Organocatalytic asymmetric [3+ 3] annulations of isatin-derived MBH carbonates and indolin-
2-imines were efficiently achieved. This appears to be the first enantioselective approach for …

Recent trends in catalytic sp 3 C–H functionalization of heterocycles

M Kaur, JF Van Humbeck - Organic & Biomolecular Chemistry, 2020‏ - pubs.rsc.org
Heterocycles are a ubiquitous substructure in organic small molecules designed for use in
materials and medicines. Recent work in catalysis has focused on enabling access to new …

[HTML][HTML] Application of biobased solvents in asymmetric catalysis

M Miele, V Pillari, V Pace, AR Alcántara, G de Gonzalo - Molecules, 2022‏ - mdpi.com
The necessity of more sustainable conditions that follow the twelve principles of Green
Chemistry have pushed researchers to the development of novel reagents, catalysts and …

Importance of Baylis-Hillman adducts in modern drug discovery

TN Reddy, VJ Rao - Tetrahedron letters, 2018‏ - Elsevier
Abstract The Baylis-Hillman (BH) reaction plays a fascinating role in the field of synthetic and
medicinal chemistry. BH adducts and their derivatives have been used as crucial synthons …