Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Modification of ground-state chemical reactivity via light–matter coherence in infrared cavities

W Ahn, JF Triana, F Recabal, F Herrera, BS Simpkins - Science, 2023 - science.org
Reaction-rate modifications for chemical processes due to strong coupling between reactant
molecular vibrations and the cavity vacuum have been reported; however, no currently …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Polariton chemistry: controlling molecular dynamics with optical cavities

RF Ribeiro, LA Martínez-Martínez, M Du… - Chemical …, 2018 - pubs.rsc.org
Molecular polaritons are the optical excitations which emerge when molecular transitions
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …

Light–matter interactions with photonic quasiparticles

N Rivera, I Kaminer - Nature Reviews Physics, 2020 - nature.com
Interactions between light and matter play an instrumental role in spectroscopy, sensing,
quantum information processing and lasers. In most of these applications, light is considered …

Strong light–matter interactions: a new direction within chemistry

M Hertzog, M Wang, J Mony, K Börjesson - Chemical Society Reviews, 2019 - pubs.rsc.org
It is possible to modify the chemical and physical properties of molecules, not only through
chemical modifications but also by coupling molecules strongly to light. More intriguingly …

Tilting a ground-state reactivity landscape by vibrational strong coupling

A Thomas, L Lethuillier-Karl, K Nagarajan… - Science, 2019 - science.org
Many chemical methods have been developed to favor a particular product in
transformations of compounds that have two or more reactive sites. We explored a different …

Molecular polaritons for controlling chemistry with quantum optics

F Herrera, J Owrutsky - The Journal of chemical physics, 2020 - pubs.aip.org
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …