Sulfonyl fluorides as targets and substrates in the development of new synthetic methods

TSB Lou, MC Willis - Nature Reviews Chemistry, 2022 - nature.com
The advent of sulfur (vi)-fluoride exchange (SuFEx) processes as transformations with click-
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …

Emerging building blocks for medicinal chemistry: recent synthetic advances

OO Grygorenko, DM Volochnyuk… - European Journal of …, 2021 - Wiley Online Library
Current medicinal chemistry relies heavily on the quality of building blocks, ie reagents used
to introduce chemical diversity into the target molecules. The last decade witnessed an …

Ethenesulfonyl fluoride (ESF) and its derivatives in SuFEx click chemistry and more

YP Meng, SM Wang, WY Fang, ZZ **e, J Leng… - …, 2020 - thieme-connect.com
The sulfur (VI) fluoride exchange reaction (SuFEx), developed by Sharpless and co-workers
in 2014, is a new category of click reaction that creates molecular connections with absolute …

Recent Advances of S–18F Radiochemistry for Positron Emission Tomography

X Deng, X Zhu - ACS omega, 2023 - ACS Publications
The click chemistry of sulfur (VI) fluoride exchange (SuFEx) has facilitated the widespread
application of sulfur–fluoride compounds such as sulfonyl fluorides, fluorosulfates, and …

State of the art procedures towards reactive [18F]fluoride in PET tracer synthesis

LYF Haveman, DJ Vugts, AD Windhorst - EJNMMI Radiopharmacy and …, 2023 - Springer
Background Positron emission tomography (PET) is a powerful, non-invasive preclinical and
clinical nuclear imaging technique used in disease diagnosis and therapy assessment …

Synthesis and 18F Labeling of Alkenyl Sulfonyl Fluorides via an Unconventional Elimination Pathway

W Zhang, X Deng, FX Zhang, JH Lin, JC **ao… - Organic …, 2022 - ACS Publications
A successful Cu-catalyzed addition of both Cl and SO2OCF2H groups into alkenes allows
us to discover the unusual reactivity of the SO2OCF2H group. As opposed to common …

Aliphatic 18F‐Radiofluorination: Recent Advances in the Labeling of Base‐Sensitive Substrates**

K Bratteby, V Shalgunov, MM Herth - ChemMedChem, 2021 - Wiley Online Library
Aliphatic fluorine‐18 radiolabeling is the most commonly used method to synthesize tracers
for PET‐imaging. With an increasing demand for 18F‐radiotracers for clinical applications …

Microfluidic synthesis of radiotracers: recent developments and commercialization prospects

M Mc Veigh, LM Bellan - Lab on a Chip, 2024 - pubs.rsc.org
Positron emission tomography (PET) is a powerful diagnostic tool that holds incredible
potential for clinicians to track a wide variety of biological processes using specialized …

Fluorine‐18 Radiolabelling and Photophysical Characteristics of Multimodal PET–Fluorescence Molecular Probes

MA Klenner, G Pascali, M Massi… - Chemistry–A European …, 2021 - Wiley Online Library
Positron emission tomography (PET)–fluorescence imaging is an emerging field of
multimodality imaging seeking to attain synergy between the two techniques. The probes …

Synthesis of 18F-Labeled Aryl Fluorosulfates via Nucleophilic Radiofluorination

YD Kwon, MH Jeon, NK Park, JK Seo, J Son… - Organic …, 2020 - ACS Publications
Sulfuryl fluoride gas is a key reagent for SO2F transfer. However, conventional SO2F
transfer reactions have limited 18F-radiochemistry translation, due to the inaccessibility of …