Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

Catalytic applications of vanadium: a mechanistic perspective

RR Langeslay, DM Kaphan, CL Marshall… - Chemical …, 2018 - ACS Publications
The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present
review, reactions catalyzed by homogeneous and supported vanadium complexes from …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Tandem Catalysis for Hydrogenation of CO and CO2 to Lower Olefins with Bifunctional Catalysts Composed of Spinel Oxide and SAPO-34

X Liu, M Wang, H Yin, J Hu, K Cheng, J Kang… - Acs …, 2020 - ACS Publications
Transformation of syngas (H2/CO) and hydrogenation of CO2 into lower olefins are attractive
routes for chemical utilization of various carbon resources and CO2, but both suffer from …

The comparison between single atom catalysis and surface organometallic catalysis

MK Samantaray, V D'Elia, E Pump, L Falivene… - Chemical …, 2019 - ACS Publications
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …

Homolytic H2 dissociation for enhanced hydrogenation catalysis on oxides

C Yang, S Ma, Y Liu, L Wang, D Yuan, WP Shao… - Nature …, 2024 - nature.com
The limited surface coverage and activity of active hydrides on oxide surfaces pose
challenges for efficient hydrogenation reactions. Herein, we quantitatively distinguish the …

Silicalite-1 stabilizes Zn-hydride species for efficient propane dehydrogenation

S Song, K Yang, P Zhang, Z Wu, J Li, H Su, S Dai… - ACS …, 2022 - ACS Publications
Propane dehydrogenation (PDH) is promising for producing high value-added propylene.
The discovery of a more efficient, economical, and nontoxic PDH catalyst is of great …

State-of-the-art catalysts for direct dehydrogenation of propane to propylene

ZP Hu, D Yang, Z Wang, ZY Yuan - Chinese Journal of Catalysis, 2019 - Elsevier
With growing demand for propylene and increasing production of propane from shale gas,
the technologies of propylene production, including direct dehydrogenation and oxidative …

Highly productive propane dehydrogenation catalyst using silica-supported Ga–Pt nanoparticles generated from single-sites

K Searles, KW Chan, JA Mendes Burak… - Journal of the …, 2018 - ACS Publications
The development of more effective alkane dehydrogenation catalysts is a key technological
challenge for the production of olefins from shale gas, an abundant source of light …

Complex hydrides for energy storage, conversion, and utilization

T He, H Cao, P Chen - Advanced Materials, 2019 - Wiley Online Library
Functional materials are the key enabling factor in the development of clean energy
technologies. Materials of particular interest, which are reviewed herein, are a class of …