Expanded theory of H-and J-molecular aggregates: the effects of vibronic coupling and intermolecular charge transfer

NJ Hestand, FC Spano - Chemical reviews, 2018 - ACS Publications
The electronic excited states of molecular aggregates and their photophysical signatures
have long fascinated spectroscopists and theoreticians alike since the advent of Frenkel …

Organic optoelectronic materials: mechanisms and applications

O Ostroverkhova - Chemical reviews, 2016 - ACS Publications
Organic (opto) electronic materials have received considerable attention due to their
applications in thin-film-transistors, light-emitting diodes, solar cells, sensors, photorefractive …

Molecular aggregate photophysics beyond the Kasha model: novel design principles for organic materials

NJ Hestand, FC Spano - Accounts of chemical research, 2017 - ACS Publications
Conspectus The transport and photophysical properties of organic molecular aggregates,
films, and crystals continue to receive widespread attention, driven mainly by expanding …

Perylene diimide-based Hj-and hJ-aggregates: the prospect of exciton band shape engineering in organic materials

A Oleson, T Zhu, IS Dunn, D Bialas, Y Bai… - The Journal of …, 2019 - ACS Publications
The exciton band dispersion in π-stacks of conjugated organic chromophores is a critical
factor in determining the photophysical response and transport properties. In such stacks …

Discrete π-stacks of perylene bisimide dyes within folda-dimers: insight into long-and short-range exciton coupling

C Kaufmann, D Bialas, M Stolte… - Journal of the American …, 2018 - ACS Publications
Four well-defined π-stacks of perylene bisimide (PBI) dyes were obtained in solution by
covalent linkage of two chromophores with spacer units of different length and sterical …

Assembly induced super-large red-shifted absorption: the burgeoning field of organic near-infrared materials

L Zhao, X Ren, X Yan - Ccs Chemistry, 2021 - chinesechemsoc.org
Supramolecular assembly of organic dye compounds with J-aggregation leads to a red-
shifted absorption spectrum that greatly facilitates the construction of near-infrared (NIR) …

Interference between Coulombic and CT-mediated couplings in molecular aggregates: H-to J-aggregate transformation in perylene-based π-stacks

NJ Hestand, FC Spano - The Journal of chemical physics, 2015 - pubs.aip.org
The spectroscopic differences between J and H-aggregates are traditionally attributed to the
spatial dependence of the Coulombic coupling, as originally proposed by Kasha. However …

Exciton annihilation in molecular aggregates suppressed through quantum interference

S Kumar, IS Dunn, S Deng, T Zhu, Q Zhao… - Nature …, 2023 - nature.com
Abstract Exciton–exciton annihilation (EEA), an important loss channel in optoelectronic
devices and photosynthetic complexes, has conventionally been assumed to be an …

Influence of Molecular Separation on Through‐Space Intervalence Transient Charge Transfer in Metal–Organic Frameworks with Cofacially arranged Redox Pairs

A Nath, V Kumar, A Shukla, HN Ghosh… - Angewandte Chemie …, 2023 - Wiley Online Library
We demonstrate direct evidence of photoinduced through‐space intervalence charge
transfer (IVCT) between two cofacially arranged redox‐active pairs in metal–organic …

Extended-charge-transfer excitons in crystalline supramolecular photocatalytic scaffolds

NJ Hestand, RV Kazantsev… - Journal of the …, 2016 - ACS Publications
Coupling among chromophores in molecular assemblies is responsible for phenomena
such as resonant energy transfer and intermolecular charge transfer. These processes are …