The direct introduction of diverse fluorinated motifs into feedstock molecules and advanced
intermediates is widely studied in pharmaceutical research and drug development. Among …

Recently, photoinduced radical difluoromethylation has emerged as a step-economical
synthetic method of CHF2-containing compounds. In this article, difluoromethylation of …

Photocatalytic reduction of molecular oxygen is a promising route toward sustainable
production of hydrogen peroxide (H2O2). This challenging process requires photoactive …

The application of piezoelectricity for the generation of trifluoromethyl (CF3) radicals is
reported together with the development of a method for the mechanochemical C− H …

Photoredox catalysis has proven to be a powerful tool in synthetic organic chemistry. The
rational design of photosensitizers with improved photocatalytic performance constitutes a …

Organic photoredox catalysts (OPCs) have the potential to replace precious-metal-based
photoredox catalysts (PMPCs). Compared with strongly oxidizing OPCs, such as the …

In the last years, an increasing interest towards the development of novel enantioselective
strategies in photocatalysis has been observed within the research community. The high …

9-(2, 6-Dimethylphenyl)-10-methylacridinium perchlorate ([Acr+–Xyl] ClO4–), 9-(4-chloro-2,
6-dimethylphenyl)-10-methylacridinium perchlorate ([Acr+–XylCl] ClO4–), and 9-(4-fluoro-2 …

Monofluoromethyl (CH2F) radical can be easily generated from a sulfoximine-based
precursor (CH2F–S (= O)(= NTs)-Ph) by the action of visible-light metal-free photoredox …

Recent years have witnessed a growing interest in the development of novel synthetic
methods and new reagents for the synthesis of difluoromethylated compounds. Dozens of …