Halogen-mediated conversion of hydrocarbons to commodities
Halogen chemistry plays a central role in the industrial manufacture of various important
chemicals, pharmaceuticals, and polymers. It involves the reaction of halogens or halides …
chemicals, pharmaceuticals, and polymers. It involves the reaction of halogens or halides …
Recent advances in energy-efficient chlorine production via HCl electrolysis
Chlorine (Cl2) is one of the most important and prime feeding reactants in the chemical
industries, but around half of the chlorine employed in the industry gets converted into …
industries, but around half of the chlorine employed in the industry gets converted into …
Facile synthesis of CuCr2O4/BiOBr nanocomposite and its photocatalytic activity towards RhB and tetracycline hydrochloride degradation under household visible …
Here we report the development of CuCr 2 O 4/BiOBr nanocomposite photocatalysts for the
first time to serve the purpose of rhodamine B (RhB) and tetracycline hydrochloride (TC-HCl) …
first time to serve the purpose of rhodamine B (RhB) and tetracycline hydrochloride (TC-HCl) …
Computational design of spinel oxides through coverage-dependent screening on the reaction phase diagram
Binary spinel-type metal oxides provide additional opportunities to achieve various catalytic
reactions. However, the complexity of the catalytic reaction network, particularly the one …
reactions. However, the complexity of the catalytic reaction network, particularly the one …
CuCrO2 Delafossite: A Stable Copper Catalyst for Chlorine Production
Around 1870, Henry Deacon discovered a process to valorize the large amounts of gaseous
HCl, originating as a by-product of the Leblanc process, by catalytic oxidation to Cl2,[1] …
HCl, originating as a by-product of the Leblanc process, by catalytic oxidation to Cl2,[1] …
What makes a good catalyst for the Deacon process?
H Over, R Schomäcker - ACS Catalysis, 2013 - ACS Publications
The Deacon process is a sustainable way to recover chlorine from HCl by its oxidation with
molecular oxygen. Deacon catalysts need to fulfill both selection criteria: high activity and …
molecular oxygen. Deacon catalysts need to fulfill both selection criteria: high activity and …
Active, selective and robust Pd and/or Cr catalysts supported on Ti-, Zr-or [Ti, Zr]-pillared montmorillonites for destruction of chlorinated volatile organic compounds
A Michalik-Zym, R Dula, D Duraczyńska… - Applied Catalysis B …, 2015 - Elsevier
Pd and/or Cr catalysts supported on Ti-, Zr-or mixed [Ti, Zr]-pillared montomorillonite clays
(PILC), for use in combustion of dichloromethane (DCM) and trichloroethylene (TCE), were …
(PILC), for use in combustion of dichloromethane (DCM) and trichloroethylene (TCE), were …
Synthesis and characterization of nanocrystalline copper–chromium catalyst and its application in the oxidation of carbon monoxide
Abstract Nanocrystalline Cu–Cr mixed oxides catalysts with different molar ratios of Cu/Cr
were synthesized by the hydrothermal method and employed in the catalytic CO oxidation …
were synthesized by the hydrothermal method and employed in the catalytic CO oxidation …
HCl Oxidation on IrO2-Based Catalysts: From Fundamentals to Scale-Up
IrO2 has been investigated as alternative rutile-type catalyst to RuO2 for gas-phase HCl
oxidation. The HCl conversion level over IrO2 at 723 K was comparable to that of RuO2 at …
oxidation. The HCl conversion level over IrO2 at 723 K was comparable to that of RuO2 at …
Depleted uranium catalysts for chlorine production
This study demonstrates depleted uranium as a remarkable heterogeneous catalyst for the
oxidation of HCl to Cl2. This reaction comprises a sustainable approach to valorise …
oxidation of HCl to Cl2. This reaction comprises a sustainable approach to valorise …