Copper–oxygen adducts: new trends in characterization and properties towards C–H activation
J De Tovar, R Leblay, Y Wang, L Wojcik… - Chemical …, 2024 - pubs.rsc.org
This review summarizes the latest discoveries in the field of C–H activation by copper
monoxygenases and more particularly by their bioinspired systems. This work first describes …
monoxygenases and more particularly by their bioinspired systems. This work first describes …
Structural Snapshots, Trajectory and Thermodynamics of the Reversible μ‐1, 2‐Peroxo/μ‐1, 1‐Hydroperoxo Dicopper (II) Interconversion
CJ Spyra, D Hiller, KA Eisenlohr, S Dechert… - Angewandte …, 2024 - Wiley Online Library
Hydrogen bonds involving the oxygen atoms of intermediates that result from copper‐
mediated O2 activation play a key role for controlling the reactivity of Cux/O2 active sites in …
mediated O2 activation play a key role for controlling the reactivity of Cux/O2 active sites in …
Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper O2-Derived Peroxide Complexes
The chemistry of copper-dioxygen complexes is relevant to copper enzymes in biology as
well as in (ligand) Cu–O2 (or Cu2–O2) species utilized in oxidative transformations. For …
well as in (ligand) Cu–O2 (or Cu2–O2) species utilized in oxidative transformations. For …
Synthetic Copper-(Di) oxygen Complex Generation and Reactivity Relevant to Copper Protein O2-Processing
Copper-(di) oxygen derived species, ie, Cun (n= 1-4) superoxide, peroxide, hydroperoxide
or oxyl (Cu–O•), participate as crucial intermediates in various critically important …
or oxyl (Cu–O•), participate as crucial intermediates in various critically important …
Direct coordination of phenol reductants to copper enables the Cu (II) reduction in Lytic polysaccharide monooxygenases
L Liao, J Kuang, W Peng, P Wu, X Sang, H Yin, C Tian… - 2024 - chemrxiv.org
Copper-dependent lytic polysaccharide monooxygenases (LPMOs) are key enzymes
involved in the breakdown of recalcitrant polysaccharides such as cellulose and chitin …
involved in the breakdown of recalcitrant polysaccharides such as cellulose and chitin …