The transition-metal-catalyzed addition of C–H bonds to carbonyls, imines, and related
polarized π bonds has emerged as a particularly efficient and powerful approach for the …

Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

The various applications of hydrogen isotopes (deuterium, D, and tritium, T) in the physical
and life sciences demand a range of methods for their installation in an array of molecular …

The exponential increase in the number of catalytic transformations that involve a metal‐
promoted activation of hitherto considered inert C− H bonds is promoting a fundamental …

Transition metal-catalyzed C–H functionalization has evolved into a prominent and
indispensable tool in organic synthesis. While nitrogen, phosphorus and sulfur-based …

Rhodium (III)-catalyzed direct functionalization of C–H bonds under oxidative conditions
leading to C–C, C–N, and C–O bond formation is reviewed. Various arene substrates …

A unique synthetic utility of a Cp* CoIII catalyst in comparison with related Cp* RhIII catalysts
is described. A C2-selective indole alkenylation/annulation sequence proceeded smoothly …

Multisubstituted isoquinoline and pyridine N-oxides have been prepared by Rh (III)-
catalyzed cyclization of oximes and diazo compounds via aryl and vinylic C–H activation …

The purpose of this article is to give a brief review of weak chelation-assistance as a
powerful means for the rhodium-catalyzed annulation of arenes with alkynes. The use of …

Rh (III)-catalyzed C–H activation assisted by an oxidizing directing group has evolved to a
mild and redox-economic strategy for the construction of heterocycles. Despite the success …