Ionic liquids (ILs) have unique physicochemical properties that make them advantageous for
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …

Actual palladium catalysts in synthetic transformations in reaction mixtures are usually
represented by dynamic catalytic systems that contain various interconvertible forms of metal …

Palladium nanoparticles stabilized by choline-based ionic liquids in glycerol were prepared
from Pd (II) precursors by simply heating at 80° C under argon; in this process, the water …

Metal nanoparticles have been deeply studied in the last few decades due to their attractive
physical and chemical properties, finding a wide range of applications in several fields …

Background Development of more efficient catalysts for Heck reaction is an urgent task.
Traditionally, palladium-based catalysts have played an important role in the construction of …

Thiolate-capped rhodium nanoparticles were synthesized by decomposition of the
organometallic precursors [Rh (μ-SC12H25)(COD)] 2 (I) and [Rh (μ-SC6H11)(COD)] 2 (II) …

Ionic liquids (ILs) are considered as highly useful materials for potential diverse uses such
as greener and more convenient alternatives to volatile organic solvents, reagents …

Palladium nanoparticles (PdNPs) prepared in neat glycerol containing TPPTS (tris (3-
sulfophenyl) phosphine trisodium salt) or cinchona-based alkaloids (cinchonidine …

Abstract Allylic alcohols, 1-buten-3-ol, 1-penten-3-ol and 1-octen-3-ol, reacted with aryl
iodides (iodotoluene, 4-iodotoluene, 4-iodophenol and 4-iodanisole) under Heck reaction …

Palladium nanoparticles generated from organometallic complexes in the presence of
functionalized mono-phosphines (L1-L3), in both THF and imidazolium-based ionic liquids …