Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …

Antibiotic resistance has become a critical issue, alarming the healthcare and agriculture
sectors worldwide. Thanks to rapid advancements in polymer science, antimicrobial …

In the quest for sustainable development, degradable polymers are attractive alternatives to
traditional fossil-based plastics. As monocomponent degradable polymers often suffer from …

Natural macromolecules, such as proteins and nucleic acids, display various complex
functionalities in biological systems. These functionalities depend on the macromolecular …

Sulfoxonium ylides are important synthetic precursors in various organic transformations.
Their synthetic potential was well explored in the synthesis of various bioactive natural …

Dendrimer chemistry is a fascinating and growing area of modern chemistry. Dendrimers are
macromolecular entities with unique three-dimensional topologies, multi-functionality, and …

Establishing the structure-property relationship is extremely valuable for the molecular
design of copolymers. However, machine learning (ML) models can incorporate both …

Amphiphilic gradient copolymers represent a promising alternative to extensively used block
copolymers due to their facile one‐step synthesis by statistical copolymerization of …

Herein, we describe the development of a new strategy for the synthesis of unsaturated
oligoesters via sequential metal-and reagent-free insertion of vinyl sulfoxonium ylides into …

In this study, we introduce the pioneering use of two distinct metal-catalyzed azide–alkyne
cycloaddition reactions, CuAAC and IrAAC, for the synthesis of discrete oligomers without …