We herein describe the high-valent cobalt-catalyzed C (sp3)–H functionalization of amide
derivatives with silver acetylides generated in situ. The reaction proceeds under kinetic …

The direct carboxylation of C (sp3)–H bonds with CO2 represents a challenging but highly
attractive strategy in organic synthesis. In this study, we presented a visible-light-catalyzed …

A palladium-catalyzed divergent reaction of primary benzamides using norbornene (NBE)
derivatives as a controlled switch is reported. When NBE is used as a mediator, indanones …

The daunting challenges in converting alcoholic O− H bonds with high bond‐dissociation
energy (BDE) to alkoxy radicals and harnessing those unruly reaction species largely limit …

We present an approach for ortho C (sp 2)-H acylation and intramolecular amination
reactions, employing 4-amino-benzotriazole (ABTA) as a bidentate directing group. This …

A total synthesis of the natural polycyclic phenolic compound daldiquinone was reported
derived from 1-naphthaldehyde. The synthesis utilizes regioselective peri-CH oxidation as a …

Dearomative skeletal editing of benzenoids represents a promising yet challenging strategy
for the rapid construction of high-value carbon frameworks from readily accessible starting …

The investigation of the various classes of mechanisms in modern catalysis is key to the
development of synthetic methods. The scope of the mechanistic investigations includes …